{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Barriendos I"],"funding":["Universidad de Zaragoza","European Commission","Agencia Estatal de Investigaci?n"],"pagination":["21699-21710"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11558669"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["63(45)"],"pubmed_abstract":["Silver bis(carbene) complexes featuring ditopic N-heterocyclic carbene (NHC) ligands have been synthesized which enable the assembly of supramolecular architectures via reaction with silver triflate. Through a systematic exploration of crystal structures and emissive properties, this study investigates the impact of the substituents on the NHC ditopic ligands [R-Im-2-Z-py], where R = Me, benzyl (Bz), or 2-naphthylmethyl (NaphCH<sub>2</sub>), and Z = H or Cl in the structural framework and emissive properties observed in the silver bis(carbene) or polynuclear species. Remarkably diverse structural motifs emerge in both of them, predominantly influenced by the choice of R wingtip and second by the Z substituent. Also the emissive quantum yield of the complexes is mostly governed by the selec"],"journal":["Inorganic chemistry"],"pubmed_title":["Understanding the Role of NHC Ditopic Ligand Substituents in the Molecular Diversity and Emissive Properties of Silver Complexes."],"pmcid":["PMC11558669"],"funding_grant_id":["TED2021130447BI00","E07_23R","PID2022-136861NB-I00"],"pubmed_authors":["Barriendos I","Crespo O","Gimeno MC"],"additional_accession":[]},"is_claimable":false,"name":"Understanding the Role of NHC Ditopic Ligand Substituents in the Molecular Diversity and Emissive Properties of Silver Complexes.","description":"Silver bis(carbene) complexes featuring ditopic N-heterocyclic carbene (NHC) ligands have been synthesized which enable the assembly of supramolecular architectures via reaction with silver triflate. Through a systematic exploration of crystal structures and emissive properties, this study investigates the impact of the substituents on the NHC ditopic ligands [R-Im-2-Z-py], where R = Me, benzyl (Bz), or 2-naphthylmethyl (NaphCH<sub>2</sub>), and Z = H or Cl in the structural framework and emissive properties observed in the silver bis(carbene) or polynuclear species. Remarkably diverse structural motifs emerge in both of them, predominantly influenced by the choice of R wingtip and second by the Z substituent. Also the emissive quantum yield of the complexes is mostly governed by the selec","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Nov","modification":"2025-04-04T00:38:26.154Z","creation":"2025-04-04T00:38:26.154Z"},"accession":"S-EPMC11558669","cross_references":{"pubmed":["39473062"],"doi":["10.1021/acs.inorgchem.4c02940"]}}