{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Du B"],"funding":["Chinese Academy of Sciences","Hainan University","State Key Laboratory of Supramolecular Structure and Materials","National Natural Science Foundation of China"],"pagination":["19432-19442"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11575629"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["15(46)"],"pubmed_abstract":["Unlike boron, nitrogen-containing multi-resonance emitters with thermally activated delayed fluorescence, here we report boron, sulfur (B, S)-based multi-resonance emitters with room-temperature phosphorescence (RTP) by inserting thiophene into a 5,9-dithia-13<i>b</i>-boranaphtho[3,2,1-<i>de</i>]anthracene skeleton that simultaneously realizes large singlet-triplet energy splitting and strong spin-orbital coupling, leading to efficient room-temperature phosphorescence in an amorphous state. Unlike most RTP emitters with ultraviolet excitation, the multi-resonance RTP emitters exhibit strong phosphorescence under daily-use blue/white LED lamps owing to their intense absorption in the visible-light region (400-486 nm). Meanwhile, such RTP behavior can be tuned by the number and fusing patter"],"journal":["Chemical science"],"pubmed_title":["Multi-resonance emitters with room-temperature phosphorescence in amorphous state and excited by visible light."],"pmcid":["PMC11575629"],"funding_grant_id":["52073282","52122309","91833306","sklssm2024024","XDB0520102","KYQD(ZR)22174","52261135541"],"pubmed_authors":["Du B","Tian H","Wang X","Wu Y","Shao S","Wang L"],"additional_accession":[]},"is_claimable":false,"name":"Multi-resonance emitters with room-temperature phosphorescence in amorphous state and excited by visible light.","description":"Unlike boron, nitrogen-containing multi-resonance emitters with thermally activated delayed fluorescence, here we report boron, sulfur (B, S)-based multi-resonance emitters with room-temperature phosphorescence (RTP) by inserting thiophene into a 5,9-dithia-13<i>b</i>-boranaphtho[3,2,1-<i>de</i>]anthracene skeleton that simultaneously realizes large singlet-triplet energy splitting and strong spin-orbital coupling, leading to efficient room-temperature phosphorescence in an amorphous state. Unlike most RTP emitters with ultraviolet excitation, the multi-resonance RTP emitters exhibit strong phosphorescence under daily-use blue/white LED lamps owing to their intense absorption in the visible-light region (400-486 nm). Meanwhile, such RTP behavior can be tuned by the number and fusing patter","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Nov","modification":"2025-04-04T01:45:47.114Z","creation":"2025-04-04T01:45:47.114Z"},"accession":"S-EPMC11575629","cross_references":{"pubmed":["39568913"],"doi":["10.1039/d4sc05383d"]}}