{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Jia Q"],"funding":["Special Fund Projects of Hubei Key Laboratory of Radiation Chemistry and Functional Materials","Innovation Team Project of Hubei University of Science and Technology","Research and Development Fund Project of Hubei University of Science and Technology","Hubei Provincial Natural Science Foundation of China"],"pagination":["5602"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11643244"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["29(23)"],"pubmed_abstract":["The design and synthesis of novel lanthanide-based coordination polymers (Ln-CPs) from flexible organic ligands is still attractive and challenging. In this work, two isostructural Ln-CPs with a unique 2D network, namely, [Ln<sub>2</sub>(H<sub>3</sub>L)<sub>2</sub>(DMF)]]<sub>n</sub> (Ln = Dy for <b>1</b>, Tb for <b>2</b>) based on a flexible polycarboxylic acid ligand hexakis(4-carboxylato-phenoxy)cyclotriphosphazene (H<sub>6</sub>L), have been solvothermally synthesized and structurally characterized. Significantly, it is the first observation of polycarboxylic acid ligands participating in coordination in the construction of coordination polymers in the form of semi-deprotonation. Magnetic measurements showed the presence of field-induced slow magnetic relaxation in complex <b>1</b>. Th"],"journal":["Molecules (Basel, Switzerland)"],"pubmed_title":["Synthesis, Structure, and Properties of 2D Lanthanide(III) Coordination Polymers Constructed from Cyclotriphosphazene-Functionlized Hexacarboxylate Ligand."],"pmcid":["PMC11643244"],"funding_grant_id":["2023T09","2023-25GP02","2024AFB1038","2021ZX07, 2022ZX05"],"pubmed_authors":["Jia Q","Yao Y","Li Z","Ji L","Zhu X","Wang J","Hu P"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis, Structure, and Properties of 2D Lanthanide(III) Coordination Polymers Constructed from Cyclotriphosphazene-Functionlized Hexacarboxylate Ligand.","description":"The design and synthesis of novel lanthanide-based coordination polymers (Ln-CPs) from flexible organic ligands is still attractive and challenging. In this work, two isostructural Ln-CPs with a unique 2D network, namely, [Ln<sub>2</sub>(H<sub>3</sub>L)<sub>2</sub>(DMF)]]<sub>n</sub> (Ln = Dy for <b>1</b>, Tb for <b>2</b>) based on a flexible polycarboxylic acid ligand hexakis(4-carboxylato-phenoxy)cyclotriphosphazene (H<sub>6</sub>L), have been solvothermally synthesized and structurally characterized. Significantly, it is the first observation of polycarboxylic acid ligands participating in coordination in the construction of coordination polymers in the form of semi-deprotonation. Magnetic measurements showed the presence of field-induced slow magnetic relaxation in complex <b>1</b>. Th","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Nov","modification":"2025-04-04T02:32:34.078Z","creation":"2025-04-04T02:32:34.078Z"},"accession":"S-EPMC11643244","cross_references":{"pubmed":["39683759"],"doi":["10.3390/molecules29235602"]}}