{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Paul S"],"funding":["Division of Chemistry","National Institute of General Medical Sciences"],"pagination":["15791-15803"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11648271"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["63(34)"],"pubmed_abstract":["This work details the synthesis and characterization of complexes of the form [Mn<sup>III</sup>X<sub>3</sub>(PR<sub>3</sub>)<sub>2</sub>] (X = Cl, Br, I), which is a rare type of coordination compound. Prior to this work, the only mode of synthesis was oxidizing mixtures of Mn<sup>II</sup>X<sub>2</sub> and PR<sub>3</sub> with dry air, but these procedures give low yields and variable outcomes. By taking advantage of the starting material [Mn<sup>III</sup>Cl<sub>3</sub>(OPPh<sub>3</sub>)<sub>2</sub>] (<b>1</b>) and other new strategies, we present robust synthetic protocols for both new and known Mn(III) halido phosphine complexes. In addition to [Mn<sup>III</sup>X<sub>3</sub>(PR<sub>3</sub>)<sub>2</sub>], these include [Mn<sup>III</sup>Cl<sub>2</sub>(dmpe)<sub>2</sub>]<sup>+</sup> salts an"],"journal":["Inorganic chemistry"],"pubmed_title":["Synthesis of Mn(III)X<sub>3</sub> (X = Cl, Br, I) Compounds with Phosphine (R<sub>3</sub>P) Ligands."],"pmcid":["PMC11648271"],"funding_grant_id":["R21-GM141685-01","CHE-1847933"],"pubmed_authors":["MacMillan SN","Saju A","Crawley MR","Paul S","Cohen C","Lacy DC"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis of Mn(III)X<sub>3</sub> (X = Cl, Br, I) Compounds with Phosphine (R<sub>3</sub>P) Ligands.","description":"This work details the synthesis and characterization of complexes of the form [Mn<sup>III</sup>X<sub>3</sub>(PR<sub>3</sub>)<sub>2</sub>] (X = Cl, Br, I), which is a rare type of coordination compound. Prior to this work, the only mode of synthesis was oxidizing mixtures of Mn<sup>II</sup>X<sub>2</sub> and PR<sub>3</sub> with dry air, but these procedures give low yields and variable outcomes. By taking advantage of the starting material [Mn<sup>III</sup>Cl<sub>3</sub>(OPPh<sub>3</sub>)<sub>2</sub>] (<b>1</b>) and other new strategies, we present robust synthetic protocols for both new and known Mn(III) halido phosphine complexes. In addition to [Mn<sup>III</sup>X<sub>3</sub>(PR<sub>3</sub>)<sub>2</sub>], these include [Mn<sup>III</sup>Cl<sub>2</sub>(dmpe)<sub>2</sub>]<sup>+</sup> salts an","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Aug","modification":"2025-04-04T01:31:46.789Z","creation":"2025-04-04T01:31:46.789Z"},"accession":"S-EPMC11648271","cross_references":{"pubmed":["39145692"],"doi":["10.1021/acs.inorgchem.4c01820"]}}