{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["30(71)"],"submitter":["Engelsberger FM"],"pubmed_abstract":["The structural variability of a compound class is an important criterion for the research into phosphor host lattices for phosphor-converted light-emitting diodes (pc-LEDs). Especially, nitridophosphates and the related class of imidonitridophosphates are promising candidates. Recently, the ammonothermal approach has opened a systematic access to this substance class with larger sample quantities. We present the successful ammonothermal synthesis of the imidonitridophosphate Ba<sub>4</sub>P<sub>4</sub>N<sub>8</sub>(NH)<sub>2</sub>:Eu<sup>2+</sup>. Its crystal structure is solved by X-ray diffraction and it crystallizes in space group Cc (no. 9) with lattice parameters a=12.5250(3), b=12.5566(4), c=7.3882(2) Å and β=102.9793(10)°. For the first time, adamantane-type (imido)nitridophosphate "],"journal":["Chemistry (Weinheim an der Bergstrasse, Germany)"],"pagination":["e202402743"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11653241"],"repository":["biostudies-literature"],"pubmed_title":["Ammonothermal Synthesis of Luminescent Imidonitridophosphate Ba&lt;sub&gt;4&lt;/sub&gt;P&lt;sub&gt;4&lt;/sub&gt;N&lt;sub&gt;8&lt;/sub&gt;(NH)&lt;sub&gt;2&lt;/sub&gt;:Eu&lt;sup&gt;2&lt;/sup&gt;."],"pmcid":["PMC11653241"],"pubmed_authors":["Witthaut K","Schnick W","Engelsberger FM","Pritzl RM","Schmidt PJ","Brauniger T","Steinadler J"],"additional_accession":[]},"is_claimable":false,"name":"Ammonothermal Synthesis of Luminescent Imidonitridophosphate Ba&lt;sub&gt;4&lt;/sub&gt;P&lt;sub&gt;4&lt;/sub&gt;N&lt;sub&gt;8&lt;/sub&gt;(NH)&lt;sub&gt;2&lt;/sub&gt;:Eu&lt;sup&gt;2&lt;/sup&gt;.","description":"The structural variability of a compound class is an important criterion for the research into phosphor host lattices for phosphor-converted light-emitting diodes (pc-LEDs). Especially, nitridophosphates and the related class of imidonitridophosphates are promising candidates. Recently, the ammonothermal approach has opened a systematic access to this substance class with larger sample quantities. We present the successful ammonothermal synthesis of the imidonitridophosphate Ba<sub>4</sub>P<sub>4</sub>N<sub>8</sub>(NH)<sub>2</sub>:Eu<sup>2+</sup>. Its crystal structure is solved by X-ray diffraction and it crystallizes in space group Cc (no. 9) with lattice parameters a=12.5250(3), b=12.5566(4), c=7.3882(2) Å and β=102.9793(10)°. For the first time, adamantane-type (imido)nitridophosphate ","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Dec","modification":"2025-04-18T14:40:45.136Z","creation":"2025-04-07T00:57:07.656Z"},"accession":"S-EPMC11653241","cross_references":{"pubmed":["39355989"],"doi":["10.1002/chem.202402743"]}}