biostudies-literatureUnknown30(71)Engelsberger FMThe structural variability of a compound class is an important criterion for the research into phosphor host lattices for phosphor-converted light-emitting diodes (pc-LEDs). Especially, nitridophosphates and the related class of imidonitridophosphates are promising candidates. Recently, the ammonothermal approach has opened a systematic access to this substance class with larger sample quantities. We present the successful ammonothermal synthesis of the imidonitridophosphate Ba4P4N8(NH)2:Eu2+. Its crystal structure is solved by X-ray diffraction and it crystallizes in space group Cc (no. 9) with lattice parameters a=12.5250(3), b=12.5566(4), c=7.3882(2) Å and β=102.9793(10)°. For the first time, adamantane-type (imido)nitridophosphate Chemistry (Weinheim an der Bergstrasse, Germany)e202402743https://www.ebi.ac.uk/biostudies/studies/S-EPMC11653241biostudies-literatureAmmonothermal Synthesis of Luminescent Imidonitridophosphate Ba4P4N8(NH)2:Eu2.PMC11653241Witthaut KSchnick WEngelsberger FMPritzl RMSchmidt PJBrauniger TSteinadler JfalseAmmonothermal Synthesis of Luminescent Imidonitridophosphate Ba4P4N8(NH)2:Eu2.The structural variability of a compound class is an important criterion for the research into phosphor host lattices for phosphor-converted light-emitting diodes (pc-LEDs). Especially, nitridophosphates and the related class of imidonitridophosphates are promising candidates. Recently, the ammonothermal approach has opened a systematic access to this substance class with larger sample quantities. We present the successful ammonothermal synthesis of the imidonitridophosphate Ba4P4N8(NH)2:Eu2+. Its crystal structure is solved by X-ray diffraction and it crystallizes in space group Cc (no. 9) with lattice parameters a=12.5250(3), b=12.5566(4), c=7.3882(2) Å and β=102.9793(10)°. For the first time, adamantane-type (imido)nitridophosphate 2024-01-01T00:00:00Z2024 Dec2025-04-18T14:40:45.136Z2025-04-07T00:57:07.656ZS-EPMC116532413935598910.1002/chem.202402743