{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Wang Y"],"funding":["Pioneer Talent Recruitment Program ( Category B), Chinese Academy of Sciences","Key Research and Development Program of Jiangxi Province","National Natural Science Foundation of China","Science and Technology Agency of Henan Province","National Key Research and Development Program of China"],"pagination":["e2407051"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11653596"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["11(47)"],"pubmed_abstract":["Advancing and deploying Fenton-inactive Cd that combines excellent catalytic activity, selectivity, and stability remains a serious challenge, predominantly owing to the difficulty in regulating the intrinsic electronic states and local geometric structures of such fully occupied d<sup>10</sup>s<sup>2</sup> configuration. In this work, a combination of experiments and theoretical calculations reveals that the incorporation of boron (B) enables the tuning of the average oxidation state of Cd<sup>0</sup> to Cd<sup>δ+</sup>, facilitating electron localization and implementing a different electrocatalytic preference compared to conventional d<sup>10</sup>-electron configurations. The resulting Cd(B) catalyst demonstrates high selectivity (>90% on average) in the O<sub>2</sub>-to-H<sub>2</sub>O"],"journal":["Advanced science (Weinheim, Baden-Wurttemberg, Germany)"],"pubmed_title":["Fenton-Inactive Cd Enables Highly Selective O&lt;sub&gt;2&lt;/sub&gt;-Derived Domino Reaction."],"pmcid":["PMC11653596"],"funding_grant_id":["E425C002","2020YFE0204500","21702045","222102240120","20243BBG71021","grants 21401203"],"pubmed_authors":["Deng R","Yang Y","Hao Z","Liu Q","Song S","Wang H","Wang Y","Dong Q","You H"],"additional_accession":[]},"is_claimable":false,"name":"Fenton-Inactive Cd Enables Highly Selective O&lt;sub&gt;2&lt;/sub&gt;-Derived Domino Reaction.","description":"Advancing and deploying Fenton-inactive Cd that combines excellent catalytic activity, selectivity, and stability remains a serious challenge, predominantly owing to the difficulty in regulating the intrinsic electronic states and local geometric structures of such fully occupied d<sup>10</sup>s<sup>2</sup> configuration. In this work, a combination of experiments and theoretical calculations reveals that the incorporation of boron (B) enables the tuning of the average oxidation state of Cd<sup>0</sup> to Cd<sup>δ+</sup>, facilitating electron localization and implementing a different electrocatalytic preference compared to conventional d<sup>10</sup>-electron configurations. The resulting Cd(B) catalyst demonstrates high selectivity (>90% on average) in the O<sub>2</sub>-to-H<sub>2</sub>O","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Dec","modification":"2025-04-27T00:31:47.101Z","creation":"2025-04-06T17:52:05.839Z"},"accession":"S-EPMC11653596","cross_references":{"pubmed":["39513409"],"doi":["10.1002/advs.202407051"]}}