{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Alrefai M"],"funding":["Natural Sciences and Engineering Research Council of Canada","Faculty of Engineering, McGill University"],"pagination":["312-322"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11697258"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["15(1)"],"pubmed_abstract":["Compositions of ethylene glycol dicyclopentenyl ether methacrylate (EGDEMA), a vegetable oil based alkyl methacrylate (C13MA), and furfuryl methacrylate (FMA) were terpolymerized for dual-crosslinked networks with tailored mechanical and thermal properties. Specifically, initiators for continuous activator regeneration (ICAR) atom transfer radical polymerization (ATRP) afforded materials with tailored glass transition temperature (<i>T</i> <sub>g</sub>) and incorporation of furan and norbornene functionalities within a single chain. The terpolymer with high furan and norbornene functionality (Ter2: <i>F</i> <sub>FMA</sub> = 0.42, <i>F</i> <sub>EGDEMA</sub> = 0.46, <i>F</i> <sub>C13MA</sub> = 0.12) is crosslinked to form single-crosslinked reversible networks with 1,1'-(methylenedi-4,1-phen"],"journal":["RSC advances"],"pubmed_title":["Photo-crosslinked Diels-Alder and thiol-ene polymer networks."],"pmcid":["PMC11697258"],"funding_grant_id":["Discovery Grant/RGPIN-2024-04619","Vadasz Doctoral Fellowships","Canada Graduate Scholarship"],"pubmed_authors":["Alrefai M","Maric M"],"additional_accession":[]},"is_claimable":false,"name":"Photo-crosslinked Diels-Alder and thiol-ene polymer networks.","description":"Compositions of ethylene glycol dicyclopentenyl ether methacrylate (EGDEMA), a vegetable oil based alkyl methacrylate (C13MA), and furfuryl methacrylate (FMA) were terpolymerized for dual-crosslinked networks with tailored mechanical and thermal properties. Specifically, initiators for continuous activator regeneration (ICAR) atom transfer radical polymerization (ATRP) afforded materials with tailored glass transition temperature (<i>T</i> <sub>g</sub>) and incorporation of furan and norbornene functionalities within a single chain. The terpolymer with high furan and norbornene functionality (Ter2: <i>F</i> <sub>FMA</sub> = 0.42, <i>F</i> <sub>EGDEMA</sub> = 0.46, <i>F</i> <sub>C13MA</sub> = 0.12) is crosslinked to form single-crosslinked reversible networks with 1,1'-(methylenedi-4,1-phen","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Jan","modification":"2026-05-29T14:31:29.316Z","creation":"2025-04-04T12:02:00.14Z"},"accession":"S-EPMC11697258","cross_references":{"pubmed":["39758926"],"doi":["10.1039/d4ra08072f"]}}