{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["16(6)"],"submitter":["Yadav AK"],"pubmed_abstract":["The reaction between molybdenum(ii) acetate and 5-aminoisophthalic acid (H<sub>2</sub>Iso-NH<sub>2</sub>) afforded [Mo<sub>12</sub>O<sub>12</sub>(μ<sub>2</sub>-O)<sub>12</sub>(Iso-NH<sub>2</sub>)<sub>12</sub>]<sup>12-</sup>, a novel molybdenum(v) metal-organic polyhedron (MOP) with a triangular antiprismatic shape stabilized by intramolecular N-H⋯O hydrogen bonds. The synthesis conditions, particularly the choice of solvent and reaction time, led to the precipitation of the Mo(v)-MOP in five distinct crystalline forms. These forms vary in their packing arrangements, co-crystallized solvent molecules, and counter-cations, with three phases containing dimethylammonium (dma<sup>+</sup>) and the other two containing diethylammonium (dea<sup>+</sup>). Each solvatomorph exhibits unique physical "],"journal":["Chemical science"],"pagination":["2589-2599"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11697376"],"repository":["biostudies-literature"],"pubmed_title":["Solvatomorphic diversity dictates the stability and solubility of metal-organic polyhedra."],"pmcid":["PMC11697376"],"pubmed_authors":["Gladysiak A","Jelfs KE","Wolpert EH","Ganose AM","Samel-Garloff B","Stylianou KC","Koley D","Yadav AK"],"additional_accession":[]},"is_claimable":false,"name":"Solvatomorphic diversity dictates the stability and solubility of metal-organic polyhedra.","description":"The reaction between molybdenum(ii) acetate and 5-aminoisophthalic acid (H<sub>2</sub>Iso-NH<sub>2</sub>) afforded [Mo<sub>12</sub>O<sub>12</sub>(μ<sub>2</sub>-O)<sub>12</sub>(Iso-NH<sub>2</sub>)<sub>12</sub>]<sup>12-</sup>, a novel molybdenum(v) metal-organic polyhedron (MOP) with a triangular antiprismatic shape stabilized by intramolecular N-H⋯O hydrogen bonds. The synthesis conditions, particularly the choice of solvent and reaction time, led to the precipitation of the Mo(v)-MOP in five distinct crystalline forms. These forms vary in their packing arrangements, co-crystallized solvent molecules, and counter-cations, with three phases containing dimethylammonium (dma<sup>+</sup>) and the other two containing diethylammonium (dea<sup>+</sup>). Each solvatomorph exhibits unique physical ","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Feb","modification":"2025-04-04T02:09:52.915Z","creation":"2025-04-04T02:09:52.915Z"},"accession":"S-EPMC11697376","cross_references":{"pubmed":["39759940"],"doi":["10.1039/d4sc05037a"]}}