{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Doligon C"],"funding":["Division of Chemistry","Research Corporation for Science Advancement","Division of Earth Sciences","Division of Materials Research"],"pagination":["978-985"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11752502"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["64(2)"],"pubmed_abstract":["One method of achieving spatially specific, multi-component nanoheterostructures is to combine multiple forms of post-synthetic modification. Applying cation or anion exchange to Cu<sub>2-<i>x</i></sub>S nanorods creates complex nanoheterostructures. Combining such anion and cation exchanges generates a system which uncovers the interplay between these two processes and understands the cooperativity between postsynthetic modifications more broadly. Cd<sup>2+</sup> exchange was carried out on various plasmonic and nonplasmonic Cu<sub>2-<i>x</i></sub>S/Cu<sub>2-<i>x</i></sub>Te nanoheterostructures to test how the presence of Te<sup>2-</sup> ions would affect the extent of Cd<sup>2+</sup> incorporation. Three hypotheses were presented for how the presence of Cu<sub>2-<i>x</i></sub>Te could a"],"journal":["Inorganic chemistry"],"pubmed_title":["Anion Exchange Impedes Subsequent Cation Exchange: Ion Mobility Is Altered by Vacancies and Ion Size."],"pmcid":["PMC11752502"],"funding_grant_id":["DMR-2003337","EAR-0923224","CHE-1724948","DMR-2312618","CS-PBP-2022-014"],"pubmed_authors":["Luo Q","Rudman E","Nguyen Dinh CT","Ehrenberg N","Plass KE","Doligon C"],"additional_accession":[]},"is_claimable":false,"name":"Anion Exchange Impedes Subsequent Cation Exchange: Ion Mobility Is Altered by Vacancies and Ion Size.","description":"One method of achieving spatially specific, multi-component nanoheterostructures is to combine multiple forms of post-synthetic modification. Applying cation or anion exchange to Cu<sub>2-<i>x</i></sub>S nanorods creates complex nanoheterostructures. Combining such anion and cation exchanges generates a system which uncovers the interplay between these two processes and understands the cooperativity between postsynthetic modifications more broadly. Cd<sup>2+</sup> exchange was carried out on various plasmonic and nonplasmonic Cu<sub>2-<i>x</i></sub>S/Cu<sub>2-<i>x</i></sub>Te nanoheterostructures to test how the presence of Te<sup>2-</sup> ions would affect the extent of Cd<sup>2+</sup> incorporation. Three hypotheses were presented for how the presence of Cu<sub>2-<i>x</i></sub>Te could a","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Jan","modification":"2025-04-05T11:34:14.456Z","creation":"2025-04-05T11:34:14.456Z"},"accession":"S-EPMC11752502","cross_references":{"pubmed":["39791857"],"doi":["10.1021/acs.inorgchem.4c04273"]}}