biostudies-literatureAshirov RNSF329https://www.ebi.ac.uk/biostudies/studies/S-EPMC11767494biostudies-literatureUnknown30(2)Five representatives of a novel type of di(hydroperoxy)alkane adducts of phosphine oxides have been synthesized and fully characterized, including their solubility in organic solvents. The phosphine oxide Cy<sub>3</sub>PO (<b>1</b>) has been used in combination with the corresponding aldehydes to create the adducts Cy<sub>3</sub>PO·(HOO)<sub>2</sub>CHCH<sub>3</sub> (<b>2</b>), Cy<sub>3</sub>PO·(HOO)<sub>2</sub>CHCH<sub>2</sub>CH<sub>3</sub> (<b>3</b>), Cy<sub>3</sub>PO·(HOO)<sub>2</sub>CH(CH<sub>2</sub>)<sub>2</sub>CH<sub>3</sub> (<b>4</b>), Cy<sub>3</sub>PO·(HOO)<sub>2</sub>CH(CH<sub>2</sub>)<sub>3</sub>CH<sub>3</sub> (<b>5</b>), and Cy<sub>3</sub>PO·(HOO)<sub>2</sub>CH(CH<sub>2</sub>)<sub>7</sub>CH<sub>3</sub> (<b>6</b>). All adducts crystallize easily and contain the peroxide and phosphMolecules (Basel, Switzerland)Hydrogen-Bonded Di(hydroperoxy)alkane Adducts of the Type Cy<sub>3</sub>P=O·(HOO)<sub>2</sub>CHR (R = Alkyl).PMC11767494CHE-1900100Bhuvanesh NBlumel JTodorovic MAshirov RfalseHydrogen-Bonded Di(hydroperoxy)alkane Adducts of the Type Cy<sub>3</sub>P=O·(HOO)<sub>2</sub>CHR (R = Alkyl).Five representatives of a novel type of di(hydroperoxy)alkane adducts of phosphine oxides have been synthesized and fully characterized, including their solubility in organic solvents. The phosphine oxide Cy<sub>3</sub>PO (<b>1</b>) has been used in combination with the corresponding aldehydes to create the adducts Cy<sub>3</sub>PO·(HOO)<sub>2</sub>CHCH<sub>3</sub> (<b>2</b>), Cy<sub>3</sub>PO·(HOO)<sub>2</sub>CHCH<sub>2</sub>CH<sub>3</sub> (<b>3</b>), Cy<sub>3</sub>PO·(HOO)<sub>2</sub>CH(CH<sub>2</sub>)<sub>2</sub>CH<sub>3</sub> (<b>4</b>), Cy<sub>3</sub>PO·(HOO)<sub>2</sub>CH(CH<sub>2</sub>)<sub>3</sub>CH<sub>3</sub> (<b>5</b>), and Cy<sub>3</sub>PO·(HOO)<sub>2</sub>CH(CH<sub>2</sub>)<sub>7</sub>CH<sub>3</sub> (<b>6</b>). All adducts crystallize easily and contain the peroxide and phosph2025-01-01T00:00:00Z2025 Jan2025-04-04T23:11:38.36Z2025-04-04T23:11:38.36ZS-EPMC117674943986019910.3390/molecules30020329