{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Xu Q"],"funding":["National Natural Science Foundation of China (National Science Foundation of China)"],"pagination":["1946"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11850892"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["16(1)"],"pubmed_abstract":["Rechargeable sodium-chlorine (Na-Cl<sub>2</sub>) batteries show great promise in grid energy storage applications due to their high electrochemical performance. However, the use of highly corrosive thionyl chloride (SOCl<sub>2</sub>)-based electrolytes has severely hindered their real-world applications. Here we show a non-corrosive ester (methyl dichloroacetate) as a promising alternative to SOCl<sub>2</sub>, which can form a non-corrosive electrolyte with aluminum chloride and sodium bis(fluorosulfonyl)imide for high-performance rechargeable Na-Cl<sub>2</sub> batteries. The resultant battery shows a reversible capacity of up to 1200 mAh g<sup>-1</sup> at a current density of 100 mA g<sup>-1</sup> calculated based on the mass of carbon with a discharge voltage of ~2.5 V, a wide temperatur"],"journal":["Nature communications"],"pubmed_title":["Harnessing organic electrolyte for non-corrosive and wide-temperature Na-Cl<sub>2</sub> battery."],"pmcid":["PMC11850892"],"funding_grant_id":["22209108"],"pubmed_authors":["Geng S","Ma L","Xu Q","Sun Y","Li N","Zhao X","Peng H","Shang M","Yuan B","Wang S","Zhang X","Tang S","Ouyang Z","Wang Y","Sun H","Liao M"],"additional_accession":[]},"is_claimable":false,"name":"Harnessing organic electrolyte for non-corrosive and wide-temperature Na-Cl<sub>2</sub> battery.","description":"Rechargeable sodium-chlorine (Na-Cl<sub>2</sub>) batteries show great promise in grid energy storage applications due to their high electrochemical performance. However, the use of highly corrosive thionyl chloride (SOCl<sub>2</sub>)-based electrolytes has severely hindered their real-world applications. Here we show a non-corrosive ester (methyl dichloroacetate) as a promising alternative to SOCl<sub>2</sub>, which can form a non-corrosive electrolyte with aluminum chloride and sodium bis(fluorosulfonyl)imide for high-performance rechargeable Na-Cl<sub>2</sub> batteries. The resultant battery shows a reversible capacity of up to 1200 mAh g<sup>-1</sup> at a current density of 100 mA g<sup>-1</sup> calculated based on the mass of carbon with a discharge voltage of ~2.5 V, a wide temperatur","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Feb","modification":"2025-04-03T23:35:56.414Z","creation":"2025-04-03T23:35:56.414Z"},"accession":"S-EPMC11850892","cross_references":{"pubmed":["39994293"],"doi":["10.1038/s41467-025-57316-5"]}}