{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Geng BJ"],"funding":["National Natural Science Foundation of China (National Science Foundation of China)"],"pagination":["2276"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11889154"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["16(1)"],"pubmed_abstract":["Molecular assembly has attracted wide attention in chemistry, condensed physics, molecular electronics, and materials sciences. However, it remains a great challenge to perform post-modulation on the assembled structures without the aid of externally applied fields. Herein, we demonstrate a combined full-weak-bonded interaction and fullerene-derivative strategy and achieve the post-modulation of layer-by-layer assembly with a precision of 5.0 Å. In the absence of external fields, the fullerene derivative exhibits a long-range interaction to boost the modulation of the assembly. Benefiting from that, a catalytic dose of fullerene derivative is able to modulate a large area of assembly, reminiscent of the catalyst in chemical reactions. This work provides an efficient and flexible approach f"],"journal":["Nature communications"],"pubmed_title":["Post-modulation of layer-by-layer assemblies coordinated by a catalytic dose of fullerene derivatives without external fields."],"pmcid":["PMC11889154"],"funding_grant_id":["22032004","21991130","21991131","T2222002"],"pubmed_authors":["Geng BJ","Ma ZW","Tan YZ","Yan YD","Li YF","Yan JW","Lin LX","Xie SY","Li JS","Yang Y","Tian ZQ","Diao TR","Mao BW","Deng LL"],"additional_accession":[]},"is_claimable":false,"name":"Post-modulation of layer-by-layer assemblies coordinated by a catalytic dose of fullerene derivatives without external fields.","description":"Molecular assembly has attracted wide attention in chemistry, condensed physics, molecular electronics, and materials sciences. However, it remains a great challenge to perform post-modulation on the assembled structures without the aid of externally applied fields. Herein, we demonstrate a combined full-weak-bonded interaction and fullerene-derivative strategy and achieve the post-modulation of layer-by-layer assembly with a precision of 5.0 Å. In the absence of external fields, the fullerene derivative exhibits a long-range interaction to boost the modulation of the assembly. Benefiting from that, a catalytic dose of fullerene derivative is able to modulate a large area of assembly, reminiscent of the catalyst in chemical reactions. This work provides an efficient and flexible approach f","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Mar","modification":"2025-04-18T12:58:48.956Z","creation":"2025-04-06T22:26:20.22Z"},"accession":"S-EPMC11889154","cross_references":{"pubmed":["40055322"],"doi":["10.1038/s41467-025-57626-8"]}}