{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["10(9)"],"submitter":["Swaathy R"],"pubmed_abstract":["Construction of a C-C bond via alkylation of ketones with alcohol as the alkylating source by employing hydrogen-borrowing strategy is attracting significant attention and is highly appealing due to its simplicity, cost-effectiveness, environmental benefits, and the fact that water is the only byproduct. The development of heterogeneous catalysts based on nonprecious base metals is progressing rapidly. Our newly disclosed manganese-doped cerium oxide nanocomposite (10 wt % Mn@CeO<sub>2</sub>) stands out as a cost-efficient and air-stable catalyst, synthesized through a straightforward coprecipitation method and employed for α-alkylation of ketones with primary alcohols via the hydrogen-borrowing strategy. X-ray diffraction (XRD) analysis confirms the high crystallinity of CeO<sub>2</sub>, "],"journal":["ACS omega"],"pagination":["9649-9660"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC11904652"],"repository":["biostudies-literature"],"pubmed_title":["Heterogeneous Mn@CeO&lt;sub&gt;2&lt;/sub&gt; Catalyst for α-Alkylation of Ketones with Alcohols via Hydrogen-Borrowing Strategy."],"pmcid":["PMC11904652"],"pubmed_authors":["Swaathy R","Karthikeyan S"],"additional_accession":[]},"is_claimable":false,"name":"Heterogeneous Mn@CeO&lt;sub&gt;2&lt;/sub&gt; Catalyst for α-Alkylation of Ketones with Alcohols via Hydrogen-Borrowing Strategy.","description":"Construction of a C-C bond via alkylation of ketones with alcohol as the alkylating source by employing hydrogen-borrowing strategy is attracting significant attention and is highly appealing due to its simplicity, cost-effectiveness, environmental benefits, and the fact that water is the only byproduct. The development of heterogeneous catalysts based on nonprecious base metals is progressing rapidly. Our newly disclosed manganese-doped cerium oxide nanocomposite (10 wt % Mn@CeO<sub>2</sub>) stands out as a cost-efficient and air-stable catalyst, synthesized through a straightforward coprecipitation method and employed for α-alkylation of ketones with primary alcohols via the hydrogen-borrowing strategy. X-ray diffraction (XRD) analysis confirms the high crystallinity of CeO<sub>2</sub>, ","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Mar","modification":"2025-04-04T00:32:42.091Z","creation":"2025-04-04T00:32:42.091Z"},"accession":"S-EPMC11904652","cross_references":{"pubmed":["40092788"],"doi":["10.1021/acsomega.4c10938"]}}