{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Molinillo P"],"funding":["Ministerio de Ciencia, Innovaci?n y Universidades","NextGenerationEU","European Regional Development Fund"],"pagination":["8125-8134"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12135044"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["64(16)"],"pubmed_abstract":["Nickel nanoparticles (Ni·MIC) stabilized with mesoionic 1,2,3-triazolylidene (MIC) ligands were prepared via decomposition of the [Ni(COD)<sub>2</sub>] (COD = 1,5-cyclooctadiene) complex with H<sub>2</sub> (3 bar) in the presence of 0.2 or 0.5 equiv of ligand. The obtained monodisperse and small-sized (3.2-3.8 nm) nanoparticles were characterized by high-resolution transmission electron microscopy (TEM, HRTEM) and inductively coupled plasma (ICP) analysis. Further analysis of the nickel nanoparticles by X-ray photoelectron spectroscopy (XPS) demonstrated the coordination of the MIC ligands to the metal surface. Finally, the Ni·MIC nanoparticles were applied in the isotopic H/D exchange in hydrides of group 14 elements (Si, Ge, Sn) using D<sub>2</sub> gas under relatively mild conditions (1"],"journal":["Inorganic chemistry"],"pubmed_title":["Selective H/D Exchange in E-H (E = Si, Ge, Sn) Bonds Catalyzed by 1,2,3-Triazolylidene-Stabilized Nickel Nanoparticles."],"pmcid":["PMC12135044"],"funding_grant_id":["PID2022-136570OB-I00","PID2019-104159GBI00","PRTRC17.I1","TED2021-129181B-I00"],"pubmed_authors":["Puyo M","Rendon N","Lara P","Vattier F","Beltran AM","Molinillo P","Galvez Del Postigo A","Suarez A"],"additional_accession":[]},"is_claimable":false,"name":"Selective H/D Exchange in E-H (E = Si, Ge, Sn) Bonds Catalyzed by 1,2,3-Triazolylidene-Stabilized Nickel Nanoparticles.","description":"Nickel nanoparticles (Ni·MIC) stabilized with mesoionic 1,2,3-triazolylidene (MIC) ligands were prepared via decomposition of the [Ni(COD)<sub>2</sub>] (COD = 1,5-cyclooctadiene) complex with H<sub>2</sub> (3 bar) in the presence of 0.2 or 0.5 equiv of ligand. The obtained monodisperse and small-sized (3.2-3.8 nm) nanoparticles were characterized by high-resolution transmission electron microscopy (TEM, HRTEM) and inductively coupled plasma (ICP) analysis. Further analysis of the nickel nanoparticles by X-ray photoelectron spectroscopy (XPS) demonstrated the coordination of the MIC ligands to the metal surface. Finally, the Ni·MIC nanoparticles were applied in the isotopic H/D exchange in hydrides of group 14 elements (Si, Ge, Sn) using D<sub>2</sub> gas under relatively mild conditions (1","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Apr","modification":"2025-07-26T03:06:52.804Z","creation":"2025-07-26T03:06:52.804Z"},"accession":"S-EPMC12135044","cross_references":{"pubmed":["40240314"],"doi":["10.1021/acs.inorgchem.5c00216"]}}