{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["16(28)"],"submitter":["Banerjee R"],"pubmed_abstract":["Fabricating discrete molecular cages as fullerene receptors has been a compelling task. The main objective of confining fullerene molecules is to utilize their physico-chemical properties in commonly used media in which they are insoluble. Herein, a fluorenone-based large trigonal Pd<sub>6</sub> molecular barrel (M1) was synthesized by coordination self-assembly to act as a potential fullerene trap. M1, in the presence of fullerene C<sub>70</sub>, converted to a larger Pd<sub>8</sub> tetrafacial barrel (M2) forming stable host-guest adduct, (C<sub>70</sub>)<sub>3</sub>@M2. The PF<sub>6</sub> <sup>-</sup> analogues of both M1 and (C<sub>70</sub>)<sub>3</sub>@M2 were acetonitrile soluble, generated reactive oxygen species due to the presence of photosensitizing fluorenone moieties in their b"],"journal":["Chemical science"],"pagination":["12885-12895"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12164367"],"repository":["biostudies-literature"],"pubmed_title":["Transformation of a Pd&lt;sub&gt;6&lt;/sub&gt; trifacial barrel to a Pd&lt;sub&gt;8&lt;/sub&gt; tetrafacial barrel by C&lt;sub&gt;70&lt;/sub&gt; as guest and oxidative photolysis of alkenes using the C&lt;sub&gt;70&lt;/sub&gt; encapsulated barrel under red light."],"pmcid":["PMC12164367"],"pubmed_authors":["Banerjee R","Adhikari D","Aggarwal M","Maji S","Mukherjee PS","Roy M"],"additional_accession":[]},"is_claimable":false,"name":"Transformation of a Pd&lt;sub&gt;6&lt;/sub&gt; trifacial barrel to a Pd&lt;sub&gt;8&lt;/sub&gt; tetrafacial barrel by C&lt;sub&gt;70&lt;/sub&gt; as guest and oxidative photolysis of alkenes using the C&lt;sub&gt;70&lt;/sub&gt; encapsulated barrel under red light.","description":"Fabricating discrete molecular cages as fullerene receptors has been a compelling task. The main objective of confining fullerene molecules is to utilize their physico-chemical properties in commonly used media in which they are insoluble. Herein, a fluorenone-based large trigonal Pd<sub>6</sub> molecular barrel (M1) was synthesized by coordination self-assembly to act as a potential fullerene trap. M1, in the presence of fullerene C<sub>70</sub>, converted to a larger Pd<sub>8</sub> tetrafacial barrel (M2) forming stable host-guest adduct, (C<sub>70</sub>)<sub>3</sub>@M2. The PF<sub>6</sub> <sup>-</sup> analogues of both M1 and (C<sub>70</sub>)<sub>3</sub>@M2 were acetonitrile soluble, generated reactive oxygen species due to the presence of photosensitizing fluorenone moieties in their b","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Jul","modification":"2026-03-16T08:17:12.758Z","creation":"2025-08-15T03:05:54.8Z"},"accession":"S-EPMC12164367","cross_references":{"pubmed":["40521109"],"doi":["10.1039/d5sc01015b"]}}