{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["16(35)"],"submitter":["Fan ZH"],"pubmed_abstract":["Photoinduced electron/energy transfer-reversible addition-fragmentation chain transfer (PET-RAFT) polymerization is a sustainable and powerful tool to synthesize polymers and copolymers. However, the development of large-scale production and polymerizations using sunlight irradiation remain top challenges for PET-RAFT polymerizations. In this study, conjugated cross-linked phosphine (PPh<sub>3</sub>-CHCP) was explored as a heterogeneous photocatalyst for efficient PET-RAFT polymerization. This development allowed PET-RAFT processes to achieve high monomer conversions, low dispersity and good chain-end fidelity under a broad range of wavelengths and sunlight irradiation from various monomers. The heterogeneous PPh<sub>3</sub>-CHCP photocatalyst could be easily separated and reused without o"],"journal":["Chemical science"],"pagination":["16347-16354"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12358945"],"repository":["biostudies-literature"],"pubmed_title":["Sunlight-driven photoinduced electron/energy transfer-reversible addition-fragmentation chain transfer polymerization at a large scale."],"pmcid":["PMC12358945"],"pubmed_authors":["He XY","He T","Xiao ZH","Xia L","Fan ZH","Tang LX","Liu YX","Fang WW","Yu JK","Wang XZ","Tang XN"],"additional_accession":[]},"is_claimable":false,"name":"Sunlight-driven photoinduced electron/energy transfer-reversible addition-fragmentation chain transfer polymerization at a large scale.","description":"Photoinduced electron/energy transfer-reversible addition-fragmentation chain transfer (PET-RAFT) polymerization is a sustainable and powerful tool to synthesize polymers and copolymers. However, the development of large-scale production and polymerizations using sunlight irradiation remain top challenges for PET-RAFT polymerizations. In this study, conjugated cross-linked phosphine (PPh<sub>3</sub>-CHCP) was explored as a heterogeneous photocatalyst for efficient PET-RAFT polymerization. This development allowed PET-RAFT processes to achieve high monomer conversions, low dispersity and good chain-end fidelity under a broad range of wavelengths and sunlight irradiation from various monomers. The heterogeneous PPh<sub>3</sub>-CHCP photocatalyst could be easily separated and reused without o","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Sep","modification":"2026-06-02T22:28:24.156Z","creation":"2026-04-21T03:13:18.412Z"},"accession":"S-EPMC12358945","cross_references":{"pubmed":["40836937"],"doi":["10.1039/d5sc04010h"]}}