{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["366(4)"],"submitter":["Beasley PA"],"pubmed_abstract":["Two Ru(II)-catalytic systems were developed for anti-Markovnikov regioselective hydroacyloxylations of terminal alkynes to vinylic esters. [Ru(NCCH3)6][(BF4)2] favors (E)-vinylic ester products with arylacetylenes and select carboxylic acids, whereas a Ru scorpionate complex with two electron-withdrawing ligands favors (Z)-vinylic ester isomers."],"journal":["Advanced synthesis & catalysis"],"pagination":["1013-1018"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12377056"],"repository":["biostudies-literature"],"pubmed_title":["Ligand and Substrate Effects on Regio- and Stereoselective Ru(II)-Catalyzed Hydroacyloxylations to Vinylic Esters."],"pmcid":["PMC12377056"],"pubmed_authors":["McDonald FE","Beasley PA"],"additional_accession":[]},"is_claimable":false,"name":"Ligand and Substrate Effects on Regio- and Stereoselective Ru(II)-Catalyzed Hydroacyloxylations to Vinylic Esters.","description":"Two Ru(II)-catalytic systems were developed for anti-Markovnikov regioselective hydroacyloxylations of terminal alkynes to vinylic esters. [Ru(NCCH3)6][(BF4)2] favors (E)-vinylic ester products with arylacetylenes and select carboxylic acids, whereas a Ru scorpionate complex with two electron-withdrawing ligands favors (Z)-vinylic ester isomers.","dates":{"release":"2024-01-01T00:00:00Z","publication":"2024 Feb","modification":"2026-05-09T19:10:37.877Z","creation":"2026-04-08T01:10:52.112Z"},"accession":"S-EPMC12377056","cross_references":{"pubmed":["40855865"],"doi":["10.1002/adsc.202301222"]}}