{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["64(33)"],"submitter":["Merk S"],"funding":["Bayerische Staatsministerium f?r Wirtschaft, Landesentwicklung und Energie"],"pubmed_abstract":["Lithium-ion conductors are one of the key features of all-solid-state lithium-ion batteries. To modify their properties and enable their implementation in high-performance devices, an understanding of the relationship between the crystal structure and the transport properties of the mobile species is important. Lithium phosphidotetrelates and -trielates are classes of lithium-ion conductors reaching ionic conductivities of up to 4.5 × 10<sup>-3</sup> cm<sup>-1</sup> at room temperature for ω-Li<sub>9</sub>GaP<sub>4</sub>. Here, we present the new lithium phosphidotantalate Li<sub>7</sub>TaP<sub>4</sub>, and the aliovalent substitution of Ta by Li atoms, which leads to a partial filling of octahedral voids in the structure of Li<sub>7</sub>TaP<sub>4</sub>. As a result, the lithium-ion condu"],"journal":["Inorganic chemistry"],"pagination":["16902-16911"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12381850"],"repository":["biostudies-literature"],"pubmed_title":["Boosting the Lithium-Ion Conductivity in Li&lt;sub&gt;7&lt;/sub&gt;TaP&lt;sub&gt;4&lt;/sub&gt; by Aliovalent Li versus Ta Substitution by Three Orders of Magnitude."],"pmcid":["PMC12381850"],"pubmed_authors":["Fassler TF","Baran V","Kollmannsberger S","Senyshyn A","Merk S","Zeitz S"],"additional_accession":[]},"is_claimable":false,"name":"Boosting the Lithium-Ion Conductivity in Li&lt;sub&gt;7&lt;/sub&gt;TaP&lt;sub&gt;4&lt;/sub&gt; by Aliovalent Li versus Ta Substitution by Three Orders of Magnitude.","description":"Lithium-ion conductors are one of the key features of all-solid-state lithium-ion batteries. To modify their properties and enable their implementation in high-performance devices, an understanding of the relationship between the crystal structure and the transport properties of the mobile species is important. Lithium phosphidotetrelates and -trielates are classes of lithium-ion conductors reaching ionic conductivities of up to 4.5 × 10<sup>-3</sup> cm<sup>-1</sup> at room temperature for ω-Li<sub>9</sub>GaP<sub>4</sub>. Here, we present the new lithium phosphidotantalate Li<sub>7</sub>TaP<sub>4</sub>, and the aliovalent substitution of Ta by Li atoms, which leads to a partial filling of octahedral voids in the structure of Li<sub>7</sub>TaP<sub>4</sub>. As a result, the lithium-ion condu","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Aug","modification":"2026-05-10T04:37:25.761Z","creation":"2026-04-08T01:30:04.501Z"},"accession":"S-EPMC12381850","cross_references":{"pubmed":["40789049"],"doi":["10.1021/acs.inorgchem.5c02167"]}}