<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>81(Pt 9)</volume><submitter>Devarajegowda HC</submitter><pubmed_abstract>In the title compound, C&lt;sub>26&lt;/sub>H&lt;sub>32&lt;/sub>BrClO&lt;sub>3&lt;/sub>, the dihedral angle between the 4-bromo-2-chloro-phenyl ring and the aromatic ring of (alk-yloxy)phenyl moiety is found to be 77.21 (2)°. The torsion angle associated with the ester moiety is 173.2 (2)° which is &lt;i>anti-periplanar&lt;/i>. In the crystal, inter-molecular C-H⋯O hydrogen bonding links the mol-ecules into cyclic hydrogen-bonded inversion dimers with &lt;i>R&lt;/i> &lt;sup>2&lt;/sup> &lt;sub>2&lt;/sub>(10) motifs. The mol-ecular structure is associated with an inversion centre and connected through two symmetrical C-H⋯O inter-actions, forming &lt;i>R&lt;/i> &lt;sup>2&lt;/sup> &lt;sub>2&lt;/sub>(10) inversion dimer motif. The packing is further consolidated by C-H⋯π and C-Cl⋯π inter-actions. Hirshfeld surface analysis showed that the most significan</pubmed_abstract><journal>Acta crystallographica. Section E, Crystallographic communications</journal><pagination>836-839</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC12412707</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Crystal structure and Hirshfeld surface analysis of 4-bromo-2-chloro-phenyl (&amp;lt;i&amp;gt;E&amp;lt;/i&amp;gt;)-3-[4-(undec-yloxy)phen-yl]acrylate.</pubmed_title><pmcid>PMC12412707</pmcid><pubmed_authors>Harish Kumar M</pubmed_authors><pubmed_authors>Devarajegowda HC</pubmed_authors><pubmed_authors>Palakshamurthy BS</pubmed_authors><pubmed_authors>Anil Kumar H</pubmed_authors><pubmed_authors>Srinivasa HT</pubmed_authors></additional><is_claimable>false</is_claimable><name>Crystal structure and Hirshfeld surface analysis of 4-bromo-2-chloro-phenyl (&amp;lt;i&amp;gt;E&amp;lt;/i&amp;gt;)-3-[4-(undec-yloxy)phen-yl]acrylate.</name><description>In the title compound, C&lt;sub>26&lt;/sub>H&lt;sub>32&lt;/sub>BrClO&lt;sub>3&lt;/sub>, the dihedral angle between the 4-bromo-2-chloro-phenyl ring and the aromatic ring of (alk-yloxy)phenyl moiety is found to be 77.21 (2)°. The torsion angle associated with the ester moiety is 173.2 (2)° which is &lt;i>anti-periplanar&lt;/i>. In the crystal, inter-molecular C-H⋯O hydrogen bonding links the mol-ecules into cyclic hydrogen-bonded inversion dimers with &lt;i>R&lt;/i> &lt;sup>2&lt;/sup> &lt;sub>2&lt;/sub>(10) motifs. The mol-ecular structure is associated with an inversion centre and connected through two symmetrical C-H⋯O inter-actions, forming &lt;i>R&lt;/i> &lt;sup>2&lt;/sup> &lt;sub>2&lt;/sub>(10) inversion dimer motif. The packing is further consolidated by C-H⋯π and C-Cl⋯π inter-actions. Hirshfeld surface analysis showed that the most significan</description><dates><release>2025-01-01T00:00:00Z</release><publication>2025 Sep</publication><modification>2026-04-14T03:24:55.358Z</modification><creation>2026-04-14T03:13:47.626Z</creation></dates><accession>S-EPMC12412707</accession><cross_references><pubmed>40918566</pubmed><doi>10.1107/S2056989025007078</doi></cross_references></HashMap>