{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["147(36)"],"submitter":["Herle D"],"pubmed_abstract":["Low-valent cadmium compounds have remained largely unexplored as electron reservoirs, with no precedent for their use in reduction or bond activation chemistry. Here, we address this gap by integrating low-valent aluminum into the cadmium coordination sphere. Aluminylene insertion into Cd{N(TMS)<sub>2</sub>}<sub>2</sub> affords bi- and trimetallic cadmium aluminyls <b>1</b> and <b>2</b>, featuring covalent yet tunable Al-Cd bonding. While <b>1</b> is irreversibly formed, <b>2</b> exhibits dynamic reactivity, enabling reversible [AlCp*]<sup>0</sup> transfer─a rare and previously undocumented feature in heterobimetallic aluminum chemistry. Acting as a thermodynamically stable yet chemically reactive surrogate for free Al(I), <b>2</b> enables selective Al(I) shuttling to B, Cd, Zn, and Ag sub"],"journal":["Journal of the American Chemical Society"],"pagination":["33315-33323"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12426937"],"repository":["biostudies-literature"],"pubmed_title":["Functional Al/Cd Heterometallics─From Controlled Al(I) Transfer to Nucleophilic Transfer of Cadmium Ions."],"pmcid":["PMC12426937"],"pubmed_authors":["Herle D","Sommer S","Dankert F"],"additional_accession":[]},"is_claimable":false,"name":"Functional Al/Cd Heterometallics─From Controlled Al(I) Transfer to Nucleophilic Transfer of Cadmium Ions.","description":"Low-valent cadmium compounds have remained largely unexplored as electron reservoirs, with no precedent for their use in reduction or bond activation chemistry. Here, we address this gap by integrating low-valent aluminum into the cadmium coordination sphere. Aluminylene insertion into Cd{N(TMS)<sub>2</sub>}<sub>2</sub> affords bi- and trimetallic cadmium aluminyls <b>1</b> and <b>2</b>, featuring covalent yet tunable Al-Cd bonding. While <b>1</b> is irreversibly formed, <b>2</b> exhibits dynamic reactivity, enabling reversible [AlCp*]<sup>0</sup> transfer─a rare and previously undocumented feature in heterobimetallic aluminum chemistry. Acting as a thermodynamically stable yet chemically reactive surrogate for free Al(I), <b>2</b> enables selective Al(I) shuttling to B, Cd, Zn, and Ag sub","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Sep","modification":"2026-06-01T12:05:05.145Z","creation":"2026-04-08T12:05:59.448Z"},"accession":"S-EPMC12426937","cross_references":{"pubmed":["40854073"],"doi":["10.1021/jacs.5c12746"]}}