{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["147(38)"],"submitter":["Guazzi S"],"pubmed_abstract":["The electrosynthesis of ethyl acetate (EtOAc) by oxidative esterification of aqueous (up to 20% water) ethanol (EtOH) is performed by employing the tetraruthenate polyoxometalate [Ru<sub>4</sub>(μ-O)<sub>4</sub>(μ-OH)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>(γ-SiW<sub>10</sub>O<sub>36</sub>)<sub>2</sub>]<sup>10-</sup> (Ru<sub>4</sub>POM) electrocatalyst with carbon nanohorns (CNHs) as a heterogeneous support. This strategy involves a voltage-gated electro-adsorption of Ru<sub>4</sub>POM on CNH-modified glassy carbon anodes with favorable interfacial dynamics, maintained under electrocatalytic conditions. These conditions are reached through the continuous reconstruction of the organic/inorganic interface (catch-and-release), as probed by converging thermal, microscopic, and electrochemical "],"journal":["Journal of the American Chemical Society"],"pagination":["34840-34848"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12464969"],"repository":["biostudies-literature"],"pubmed_title":["Direct Conversion of Ethanol to Ethyl Acetate by Dynamic Polyoxometalate/Carbon Nanohorn Electrocatalytic Interfaces."],"pmcid":["PMC12464969"],"pubmed_authors":["Durr RN","Cacioppo M","Bonchio M","Bassan E","Bogo A","Guazzi S","Arias-Ferreiro G","Prato M"],"additional_accession":[]},"is_claimable":false,"name":"Direct Conversion of Ethanol to Ethyl Acetate by Dynamic Polyoxometalate/Carbon Nanohorn Electrocatalytic Interfaces.","description":"The electrosynthesis of ethyl acetate (EtOAc) by oxidative esterification of aqueous (up to 20% water) ethanol (EtOH) is performed by employing the tetraruthenate polyoxometalate [Ru<sub>4</sub>(μ-O)<sub>4</sub>(μ-OH)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>(γ-SiW<sub>10</sub>O<sub>36</sub>)<sub>2</sub>]<sup>10-</sup> (Ru<sub>4</sub>POM) electrocatalyst with carbon nanohorns (CNHs) as a heterogeneous support. This strategy involves a voltage-gated electro-adsorption of Ru<sub>4</sub>POM on CNH-modified glassy carbon anodes with favorable interfacial dynamics, maintained under electrocatalytic conditions. These conditions are reached through the continuous reconstruction of the organic/inorganic interface (catch-and-release), as probed by converging thermal, microscopic, and electrochemical ","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Sep","modification":"2026-06-03T21:22:07.53Z","creation":"2026-05-01T03:10:58.93Z"},"accession":"S-EPMC12464969","cross_references":{"pubmed":["40934491"],"doi":["10.1021/jacs.5c10817"]}}