{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["16(42)"],"submitter":["Wang S"],"pubmed_abstract":["Developing dual-catalytic architectures integrating photoactive and transition metal sites holds significant potential for light-driven cross-coupling reactions. This study presents a novel strategy to create synergistic dual-catalytic architectures based on surface engineering of Ti<sub>6</sub>-oxo clusters for efficient photocatalytic formation of C-N bonds. Ti<sub>6</sub>-oxo clusters are precisely decorated with bipyridine ligands through competitive coordination, followed by the anchoring of iridium photo-sensitizers and nickel catalytic centers to the electron-rich nitrogen sites. The obtained Ni-Ir/Ti<sub>6</sub>-Bpca exhibits significantly enhanced charge transfer efficiency <i>via</i> an intramolecular electron transfer mechanism. This integrated design not only boosted catalytic "],"journal":["Chemical science"],"pagination":["19849-19856"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12465846"],"repository":["biostudies-literature"],"pubmed_title":["Dual-catalytic architectures accommodated by titanium-oxo clusters boosting visible-light-driven C-N cross-coupling &lt;i&gt;via&lt;/i&gt; intramolecular electron transfer."],"pmcid":["PMC12465846"],"pubmed_authors":["Gao Q","Wang S","Ye G","Wang Y","Jia J"],"additional_accession":[]},"is_claimable":false,"name":"Dual-catalytic architectures accommodated by titanium-oxo clusters boosting visible-light-driven C-N cross-coupling &lt;i&gt;via&lt;/i&gt; intramolecular electron transfer.","description":"Developing dual-catalytic architectures integrating photoactive and transition metal sites holds significant potential for light-driven cross-coupling reactions. This study presents a novel strategy to create synergistic dual-catalytic architectures based on surface engineering of Ti<sub>6</sub>-oxo clusters for efficient photocatalytic formation of C-N bonds. Ti<sub>6</sub>-oxo clusters are precisely decorated with bipyridine ligands through competitive coordination, followed by the anchoring of iridium photo-sensitizers and nickel catalytic centers to the electron-rich nitrogen sites. The obtained Ni-Ir/Ti<sub>6</sub>-Bpca exhibits significantly enhanced charge transfer efficiency <i>via</i> an intramolecular electron transfer mechanism. This integrated design not only boosted catalytic ","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Oct","modification":"2026-06-05T08:44:48.849Z","creation":"2026-05-14T03:12:59.333Z"},"accession":"S-EPMC12465846","cross_references":{"pubmed":["41019646"],"doi":["10.1039/d5sc04675k"]}}