{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["10(38)"],"submitter":["Kalimuthu K"],"pubmed_abstract":["2,5-Furandicarboxylic acid (FDCA) is an exceptionally promising biodegradable alternative to petroleum-derived terephthalic acid. The synthesis of FDCA from biomass-derived 5-hydroxymethylfurfural (HMF) has attracted significant attention. Herein, we report a straightforward method for synthesizing N-doped carbon-supported metal/metal phosphide catalysts developed using solid grinding techniques followed by pyrolysis. The synergistic effects of metal alloys and metal phosphides significantly influenced the product selectivity. The optimized catalyst (FeP-Co_0.2/NC) achieved a remarkable FDCA yield of 91.6% with complete HMF conversion at 150 °C for 24 h, using water as the solvent and O<sub>2</sub> as the oxidant. This study presents a sustainable and efficient approach for FDCA production. This discovery represents a sustainable method for producing FDCA with a high yield by employing environmentally friendly solvents and oxidizers."],"journal":["ACS omega"],"pagination":["44415-44424"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12489686"],"repository":["biostudies-literature"],"pubmed_title":["Oxidation of 5‑HMF Catalyzed by N‑Doped Carbon-Supported Non-Noble Metal Catalysts."],"pmcid":["PMC12489686"],"pubmed_authors":["Kalimuthu K","Poonsawat T","Somsook E","Chumkaeo P"],"additional_accession":[]},"is_claimable":false,"name":"Oxidation of 5‑HMF Catalyzed by N‑Doped Carbon-Supported Non-Noble Metal Catalysts.","description":"2,5-Furandicarboxylic acid (FDCA) is an exceptionally promising biodegradable alternative to petroleum-derived terephthalic acid. The synthesis of FDCA from biomass-derived 5-hydroxymethylfurfural (HMF) has attracted significant attention. Herein, we report a straightforward method for synthesizing N-doped carbon-supported metal/metal phosphide catalysts developed using solid grinding techniques followed by pyrolysis. The synergistic effects of metal alloys and metal phosphides significantly influenced the product selectivity. The optimized catalyst (FeP-Co_0.2/NC) achieved a remarkable FDCA yield of 91.6% with complete HMF conversion at 150 °C for 24 h, using water as the solvent and O<sub>2</sub> as the oxidant. This study presents a sustainable and efficient approach for FDCA production. This discovery represents a sustainable method for producing FDCA with a high yield by employing environmentally friendly solvents and oxidizers.","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Sep","modification":"2026-06-04T05:13:54.235Z","creation":"2026-06-01T03:06:23.39Z"},"accession":"S-EPMC12489686","cross_references":{"pubmed":["41048713"],"doi":["10.1021/acsomega.5c06288"]}}