{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["81(Pt 10)"],"submitter":["Kingsley NB"],"pubmed_abstract":["The title compound C<sub>15</sub>H<sub>8</sub>BrF<sub>6</sub>N, was prepared by a condensation reaction of 2-bromo-benzaldehyde and 3,5-bis-(tri-fluoro-meth-yl)aniline in the presence of anhydrous magnesium sulfate. The compound readily crystallizes from a concentrated hexa-nes solution in high yield. The imine bond is nearly planar with the 2-bromo-phenyl group, while the <i>N</i>-(3,5-bis-(tri-fluoro-meth-yl)phenyl moiety is significantly twisted from the imine group [49.61 (5)°]. The crystal packing involves short inter-molecular C-H⋯Br contacts linking zigzag ribbons flanked by fluorous layers."],"journal":["Acta crystallographica. Section E, Crystallographic communications"],"pagination":["916-919"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12498049"],"repository":["biostudies-literature"],"pubmed_title":["Synthesis and crystal structure of (&lt;i&gt;E&lt;/i&gt;)-&lt;i&gt;N&lt;/i&gt;-[(2-bromo-phen-yl)methyl-idene]-3,5-bis-(tri-fluoro-meth-yl)aniline."],"pmcid":["PMC12498049"],"pubmed_authors":["Doyon TJ","Janzen DE","Kingsley NB"],"additional_accession":[]},"is_claimable":false,"name":"Synthesis and crystal structure of (&lt;i&gt;E&lt;/i&gt;)-&lt;i&gt;N&lt;/i&gt;-[(2-bromo-phen-yl)methyl-idene]-3,5-bis-(tri-fluoro-meth-yl)aniline.","description":"The title compound C<sub>15</sub>H<sub>8</sub>BrF<sub>6</sub>N, was prepared by a condensation reaction of 2-bromo-benzaldehyde and 3,5-bis-(tri-fluoro-meth-yl)aniline in the presence of anhydrous magnesium sulfate. The compound readily crystallizes from a concentrated hexa-nes solution in high yield. The imine bond is nearly planar with the 2-bromo-phenyl group, while the <i>N</i>-(3,5-bis-(tri-fluoro-meth-yl)phenyl moiety is significantly twisted from the imine group [49.61 (5)°]. The crystal packing involves short inter-molecular C-H⋯Br contacts linking zigzag ribbons flanked by fluorous layers.","dates":{"release":"2025-01-01T00:00:00Z","publication":"2025 Oct","modification":"2026-05-06T03:19:05.894Z","creation":"2026-05-06T03:13:05.339Z"},"accession":"S-EPMC12498049","cross_references":{"pubmed":["41059323"],"doi":["10.1107/S2056989025007650"]}}