biostudies-literatureBenitez MEuropean Social Fund PlusGobierno de Arag?nMinisterio de Ciencia e Innovaci?nEuropean Regional Development Fund6346-6361https://www.ebi.ac.uk/biostudies/studies/S-EPMC12582129biostudies-literatureUnknown63(14)Complex IrH₅(PⁱPr₃)₂ (<b>1</b>) activates two different σ-bonds of 3-phenoxy-1-phenylisoquinoline, 2-(1<i>H</i>-benzimidazol-2-yl)-6-phenylpyridine, 2-(1<i>H</i>-indol-2-yl)-6-phenylpyridine, 2-(2-hydroxyphenyl)-6-phenylpyridine, <i>N</i>-(2-hydroxyphenyl)-<i>N</i>'-phenylimidazolylidene, and 1,3-di(2-pyridyl)-4,6-dimethylbenzene to give IrH{κ³-<i>C,N,C</i>-[C₆H₄-isoqui-O-C₆H₄]}(PⁱPr₃)₂ (<b>2</b>), IrH{κ³-<i>N,N,C</i>-[NBzim-py-C₆H₄]}(PⁱPr₃)₂ (<b>3</b>), IrH{κ³-<i>N,N,C</i>-[Ind-py-C₆H₄]}(PⁱPr₃)₂ (<b>4</b>), IrH{κ³-<i>CInorganic chemistryC-H, N-H, and O-H Bond Activations to Prepare Phosphorescent Hydride-Iridium(III)-Phosphine Emitters with Photocatalytic Achievement in C-C Coupling Reactions.PMC12582129RED2022-134287-TE06_23RPID2020-115286GB-I00Esteruelas MABuil MLMartin-Escura COnate ELopez AMBenitez MfalseC-H, N-H, and O-H Bond Activations to Prepare Phosphorescent Hydride-Iridium(III)-Phosphine Emitters with Photocatalytic Achievement in C-C Coupling Reactions.Complex IrH₅(PⁱPr₃)₂ (<b>1</b>) activates two different σ-bonds of 3-phenoxy-1-phenylisoquinoline, 2-(1<i>H</i>-benzimidazol-2-yl)-6-phenylpyridine, 2-(1<i>H</i>-indol-2-yl)-6-phenylpyridine, 2-(2-hydroxyphenyl)-6-phenylpyridine, <i>N</i>-(2-hydroxyphenyl)-<i>N</i>'-phenylimidazolylidene, and 1,3-di(2-pyridyl)-4,6-dimethylbenzene to give IrH{κ³-<i>C,N,C</i>-[C₆H₄-isoqui-O-C₆H₄]}(PⁱPr₃)₂ (<b>2</b>), IrH{κ³-<i>N,N,C</i>-[NBzim-py-C₆H₄]}(PⁱPr₃)₂ (<b>3</b>), IrH{κ³-<i>N,N,C</i>-[Ind-py-C₆H₄]}(PⁱPr₃)₂ (<b>4</b>), IrH{κ³-<i>C2024-01-01T00:00:00Z2024 Apr2026-06-05T10:47:43.615Z2026-05-16T03:08:24.985ZS-EPMC125821293854683910.1021/acs.inorgchem.4c00115