{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Li Y"],"funding":["National Science Fund for Distinguished Young Scholars","Shaanxi Fundamental Science Research Project for Chemistry & Biology"],"pagination":["e20814"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12759195"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["65(1)"],"pubmed_abstract":["Controlling the assembly of molecular nanocapsules through metal-carbon bonds constitutes a major challenge in the field of supramolecular organometallic chemistry. Here, we demonstrate the construction of two nanosized dodecanuclear organometallic capsules, [{Ag(CH<sub>3</sub>CN)<sub>4</sub>(BF<sub>4</sub>)<sub>8</sub>}⊂Ag<sub>12</sub>(1)<sub>6</sub>](BF<sub>4</sub>)<sub>5</sub> and [(CF<sub>3</sub>SO<sub>3</sub>)<sub>8</sub>⊂Ag<sub>12</sub>(1)<sub>6</sub>](CF<sub>3</sub>SO<sub>3</sub>)<sub>4</sub> from the calix[4]resorcinarene-based tetrakisimidazolium salts H<sub>4</sub>-1(X)<sub>4</sub> and Ag<sup>I</sup> ions employing the metal-carbene directed self-assembly and hierarchical template strategies. An [Ag(CH<sub>3</sub>CH)<sub>4</sub>(BF<sub>4</sub>)<sub>8</sub>]<sup>7-</sup> anion or "],"journal":["Angewandte Chemie (International ed. in English)"],"pubmed_title":["Hierarchical, Template-Controlled Self-Assembly of Two Different Organometallic Capsules from a Tetrakisimidazolium Salt."],"pmcid":["PMC12759195"],"funding_grant_id":["22025107","22JHZ003"],"pubmed_authors":["Li Y","Hahn FE","Zhang L","Chang XT","Yuan G","Han YF"],"additional_accession":[]},"is_claimable":false,"name":"Hierarchical, Template-Controlled Self-Assembly of Two Different Organometallic Capsules from a Tetrakisimidazolium Salt.","description":"Controlling the assembly of molecular nanocapsules through metal-carbon bonds constitutes a major challenge in the field of supramolecular organometallic chemistry. Here, we demonstrate the construction of two nanosized dodecanuclear organometallic capsules, [{Ag(CH<sub>3</sub>CN)<sub>4</sub>(BF<sub>4</sub>)<sub>8</sub>}⊂Ag<sub>12</sub>(1)<sub>6</sub>](BF<sub>4</sub>)<sub>5</sub> and [(CF<sub>3</sub>SO<sub>3</sub>)<sub>8</sub>⊂Ag<sub>12</sub>(1)<sub>6</sub>](CF<sub>3</sub>SO<sub>3</sub>)<sub>4</sub> from the calix[4]resorcinarene-based tetrakisimidazolium salts H<sub>4</sub>-1(X)<sub>4</sub> and Ag<sup>I</sup> ions employing the metal-carbene directed self-assembly and hierarchical template strategies. An [Ag(CH<sub>3</sub>CH)<sub>4</sub>(BF<sub>4</sub>)<sub>8</sub>]<sup>7-</sup> anion or ","dates":{"release":"2026-01-01T00:00:00Z","publication":"2026 Jan","modification":"2026-06-06T09:37:40.363Z","creation":"2026-05-28T03:12:17.515Z"},"accession":"S-EPMC12759195","cross_references":{"pubmed":["41231044"],"doi":["10.1002/anie.202520814"]}}