{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Zhang J"],"funding":["National Key R&D Program of China","China Postdoctoral Science Foundation","National Natural Science Foundation of China","National Key Research and Development Program of China","Natural Science Foundation of Jiangsu Province"],"pagination":["e10894"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12810596"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["38(4)"],"pubmed_abstract":["Low-temperature lithium metal batteries (LT-LMBs) are increasingly desired for higher energy density and longer lifespan. However, due to organic electrolyte solidification, LT-LMBs are impeded by huge barriers resulting from the hindrance of larger solvation shells with strong ion-dipole interactions, leading to depressive Li kinetics and severe dendrite formation. Herein, interfacial catalysis by constructing electron delocalization d-orbital metal oxides toward the ion-dipole interactions is pioneered to accelerate the larger Li(solvents)<sub>x</sub> <sup>+</sup> dissociation under the low-temperature environment. Specifically, various kinds of d-orbital metal oxides (M = Ti, V, Fe, Co) with oxygen defect modulation are systematically screened and investigated for breaking the ion-dipol"],"journal":["Advanced materials (Deerfield Beach, Fla.)"],"pubmed_title":["Taming Interfacial Ion-Dipole Interactions With d-Orbital Delocalized Electron Catalysis Expediates Low-Temperature Li Metal Batteries."],"pmcid":["PMC12810596"],"funding_grant_id":["2023M732561","21972164","22572217","52171191","2021YFA1201503","52371198","BK 20210130","2023M731084","22309144","22279161"],"pubmed_authors":["Liu H","Wu J","Zhang J","Liu M","Yin S","Guan Q","He R","Jia L","Wang J","Li X","Cao Z","Zhang Y","You C","Miao Y","Lin H","Tian N","Liu F"],"additional_accession":[]},"is_claimable":false,"name":"Taming Interfacial Ion-Dipole Interactions With d-Orbital Delocalized Electron Catalysis Expediates Low-Temperature Li Metal Batteries.","description":"Low-temperature lithium metal batteries (LT-LMBs) are increasingly desired for higher energy density and longer lifespan. However, due to organic electrolyte solidification, LT-LMBs are impeded by huge barriers resulting from the hindrance of larger solvation shells with strong ion-dipole interactions, leading to depressive Li kinetics and severe dendrite formation. Herein, interfacial catalysis by constructing electron delocalization d-orbital metal oxides toward the ion-dipole interactions is pioneered to accelerate the larger Li(solvents)<sub>x</sub> <sup>+</sup> dissociation under the low-temperature environment. Specifically, various kinds of d-orbital metal oxides (M = Ti, V, Fe, Co) with oxygen defect modulation are systematically screened and investigated for breaking the ion-dipol","dates":{"release":"2026-01-01T00:00:00Z","publication":"2026 Jan","modification":"2026-06-06T15:37:47.054Z","creation":"2026-06-02T03:08:45.065Z"},"accession":"S-EPMC12810596","cross_references":{"pubmed":["41074733"],"doi":["10.1002/adma.202510894"]}}