{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Elcheikh Mahmoud M"],"funding":["Jacobs University","Agentúra na Podporu Výskumu a Vývoja","Deutsche Forschungsgemeinschaft","Vedecká Grantová Agentúra MŠVVaŠ SR a SAV"],"pagination":["1051-1064"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC12820969"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["65(2)"],"pubmed_abstract":["We report on the synthesis of the lanthanide-containing 17-tungsto-1-phosphates [Ln(P(H<sub>4</sub>)W<sub>17</sub>O<sub>61</sub>)<sub>2</sub>]<sup>19-</sup> (Ln = La<sup>3+</sup>, Ce<sup>3+</sup>, Eu<sup>3+</sup>, Gd<sup>3+</sup>, Yb<sup>3+</sup>, Lu<sup>3+</sup>, Y<sup>3+</sup>), comprising a lanthanide ion connecting two [P(H<sub>4</sub>)W<sub>17</sub>O<sub>61</sub>]<sup>11-</sup> units in a <i>syn</i>-configuration. The compounds were characterized in the solid state by IR, powder XRD, and TGA, and in solution by <sup>31</sup>P and <sup>183</sup>W NMR. Alternating current magnetic susceptibility investigations revealed the Ce<sup>3+</sup> and Yb<sup>3+</sup> analogues to be single-molecule magnets (SMM), which was further corroborated by sub-kelvin temperature μSQUID studies. For the Eu"],"journal":["Inorganic chemistry"],"pubmed_title":["Reactivity of the Asymmetric Wells-Dawson Ion: Lanthanide-Containing 34-Tungsto-2-Phosphates [Ln(P(H&lt;sub&gt;4&lt;/sub&gt;)W&lt;sub&gt;17&lt;/sub&gt;O&lt;sub&gt;61&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;19-&lt;/sup&gt; (Ln = La&lt;sup&gt;3+&lt;/sup&gt;, Ce&lt;sup&gt;3+&lt;/sup&gt;, Eu&lt;sup&gt;3+&lt;/sup&gt;, Gd&lt;sup&gt;3+&lt;/sup&gt;, Yb&lt;sup&gt;3+&lt;/sup&gt;, Lu&lt;sup&gt;3+&lt;/sup&gt;, Y&lt;sup&gt;3+&lt;/sup&gt;)."],"pmcid":["PMC12820969"],"funding_grant_id":["APVV-22-0172","KO-2288/33-1","KO-2288/31-1","APVV-23-0006","VEGA 1/0029/22"],"pubmed_authors":["Elcheikh Mahmoud M","Molina-Jiron C","Sarkar A","Malinova N","Kim JO","Kortz U","Kuppusamy SK","Moreno-Pineda E","Bassil BS","Sunil A","Wernsdorfer W","Ruben M"],"additional_accession":[]},"is_claimable":false,"name":"Reactivity of the Asymmetric Wells-Dawson Ion: Lanthanide-Containing 34-Tungsto-2-Phosphates [Ln(P(H&lt;sub&gt;4&lt;/sub&gt;)W&lt;sub&gt;17&lt;/sub&gt;O&lt;sub&gt;61&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;19-&lt;/sup&gt; (Ln = La&lt;sup&gt;3+&lt;/sup&gt;, Ce&lt;sup&gt;3+&lt;/sup&gt;, Eu&lt;sup&gt;3+&lt;/sup&gt;, Gd&lt;sup&gt;3+&lt;/sup&gt;, Yb&lt;sup&gt;3+&lt;/sup&gt;, Lu&lt;sup&gt;3+&lt;/sup&gt;, Y&lt;sup&gt;3+&lt;/sup&gt;).","description":"We report on the synthesis of the lanthanide-containing 17-tungsto-1-phosphates [Ln(P(H<sub>4</sub>)W<sub>17</sub>O<sub>61</sub>)<sub>2</sub>]<sup>19-</sup> (Ln = La<sup>3+</sup>, Ce<sup>3+</sup>, Eu<sup>3+</sup>, Gd<sup>3+</sup>, Yb<sup>3+</sup>, Lu<sup>3+</sup>, Y<sup>3+</sup>), comprising a lanthanide ion connecting two [P(H<sub>4</sub>)W<sub>17</sub>O<sub>61</sub>]<sup>11-</sup> units in a <i>syn</i>-configuration. The compounds were characterized in the solid state by IR, powder XRD, and TGA, and in solution by <sup>31</sup>P and <sup>183</sup>W NMR. Alternating current magnetic susceptibility investigations revealed the Ce<sup>3+</sup> and Yb<sup>3+</sup> analogues to be single-molecule magnets (SMM), which was further corroborated by sub-kelvin temperature μSQUID studies. For the Eu","dates":{"release":"2026-01-01T00:00:00Z","publication":"2026 Jan","modification":"2026-06-06T18:10:34.069Z","creation":"2026-06-04T03:11:08.885Z"},"accession":"S-EPMC12820969","cross_references":{"pubmed":["41481903"],"doi":["10.1021/acs.inorgchem.5c04807"]}}