{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Keck GE"],"funding":["NIGMS NIH HHS"],"pagination":["3687-90"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC1480409"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["4(21)"],"pubmed_abstract":["[reaction: see text] Previously unknown intramolecular Baylis-Hillman and Morita reactions involving cyclization of an unsaturated thiol ester onto a pendant aldehyde function are reported. These can be used successfully for the preparation of both cyclopentenols and cyclohexenols, but the results are very sensitive to substrate and precise reaction conditions."],"journal":["Organic letters"],"pubmed_title":["Intramolecular Baylis-Hillman and morita reactions using unsaturated thiol ester substrates containing enolizable aldehydes."],"pmcid":["PMC1480409"],"funding_grant_id":["R01 GM028961","GM-28961"],"pubmed_authors":["Welch DS","Keck GE"],"additional_accession":[]},"is_claimable":false,"name":"Intramolecular Baylis-Hillman and morita reactions using unsaturated thiol ester substrates containing enolizable aldehydes.","description":"[reaction: see text] Previously unknown intramolecular Baylis-Hillman and Morita reactions involving cyclization of an unsaturated thiol ester onto a pendant aldehyde function are reported. These can be used successfully for the preparation of both cyclopentenols and cyclohexenols, but the results are very sensitive to substrate and precise reaction conditions.","dates":{"release":"2002-01-01T00:00:00Z","publication":"2002 Oct","modification":"2020-10-29T10:34:29Z","creation":"2019-03-27T01:45:29Z"},"accession":"S-EPMC1480409","cross_references":{"pubmed":["12375919"],"doi":["10.1021/ol026638s"]}}