{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Li Y"],"funding":["NIGMS NIH HHS"],"pagination":["1391-1397"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2084221"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["18(12)"],"pubmed_abstract":["The ability of commercially available amino acid derivatives, especially Fmoc-Trp(Boc)-OH, to differentiate enantiomers of chiral phosphonates, phosphinates, phosphates, phosphine oxides, and phosphonamidates is demonstrated with (31)P, (13)C, and (1)H NMR spectroscopy. The chiral differentiation provided a rapid and convenient method for measuring the enantiomeric purity of these phosphorus compounds."],"journal":["Tetrahedron, asymmetry"],"pubmed_title":["Differentiation of chiral phosphorus enantiomers by P and H NMR spectroscopy using amino acid derivatives as chemical solvating agents."],"pmcid":["PMC2084221"],"funding_grant_id":["R01 GM068550","R01 GM068550-04"],"pubmed_authors":["Li Y","Raushel FM"],"additional_accession":[]},"is_claimable":false,"name":"Differentiation of chiral phosphorus enantiomers by P and H NMR spectroscopy using amino acid derivatives as chemical solvating agents.","description":"The ability of commercially available amino acid derivatives, especially Fmoc-Trp(Boc)-OH, to differentiate enantiomers of chiral phosphonates, phosphinates, phosphates, phosphine oxides, and phosphonamidates is demonstrated with (31)P, (13)C, and (1)H NMR spectroscopy. The chiral differentiation provided a rapid and convenient method for measuring the enantiomeric purity of these phosphorus compounds.","dates":{"release":"2007-01-01T00:00:00Z","publication":"2007 Jul","modification":"2025-04-04T14:48:19.51Z","creation":"2019-03-27T02:21:59Z"},"accession":"S-EPMC2084221","cross_references":{"pubmed":["18037983"],"doi":["10.1016/j.tetasy.2007.06.012"]}}