biostudies-literatureMolander GANCRR NIH HHSNIGMS NIH HHS9198-202https://www.ebi.ac.uk/biostudies/studies/S-EPMC2515367biostudies-literatureUnknown71(24)[reaction: see text] The palladium-catalyzed cross-coupling of potassium aryltrifluoroborates with benzylic halides occurs in good yield with high functional group tolerance. The increased stability of potassium aryltrifluoroborates compared to other boron coupling partners makes this an effective route to functionalized methylene-linked biaryl systems.The Journal of organic chemistrySuzuki-Miyaura cross-coupling reactions of benzyl halides with potassium aryltrifluoroborates.PMC2515367R01 GM035249R01 GM035249-22GM35249S10 RR016640-01Elia MDMolander GAfalseSuzuki-Miyaura cross-coupling reactions of benzyl halides with potassium aryltrifluoroborates.[reaction: see text] The palladium-catalyzed cross-coupling of potassium aryltrifluoroborates with benzylic halides occurs in good yield with high functional group tolerance. The increased stability of potassium aryltrifluoroborates compared to other boron coupling partners makes this an effective route to functionalized methylene-linked biaryl systems.2006-01-01T00:00:00Z2006 Nov2025-04-19T07:38:11.141Z2019-03-26T23:28:27ZS-EPMC25153671710954710.1021/jo061699f