biostudies-literature00640Trost BMNIGMS NIH HHS2027-30https://www.ebi.ac.uk/biostudies/studies/S-EPMC2565574biostudies-literatureUnknown8(10)[reaction; see text] The asymmetric synthesis of the oxindole alkaloid horsfiline is described. A palladium-catalyzed asymmetric allylic alkylation (AAA) is used to set the spiro(pyrrolidine-oxindole) stereogenic center.Organic lettersPalladium asymmetric allylic alkylation of prochiral nucleophiles: horsfiline.PMC2565574GM33049R01 GM033049-31R01 GM033049Trost BMBrennan MK64falsePalladium asymmetric allylic alkylation of prochiral nucleophiles: horsfiline.[reaction; see text] The asymmetric synthesis of the oxindole alkaloid horsfiline is described. A palladium-catalyzed asymmetric allylic alkylation (AAA) is used to set the spiro(pyrrolidine-oxindole) stereogenic center.2006-01-01T00:00:00Z2006 May2024-10-18T21:00:51.917Z2019-03-27T00:18:49ZS-EPMC25655741667177310.1021/ol060298j