biostudies-literatureCheng GNIGMS NIH HHS4545-8https://www.ebi.ac.uk/biostudies/studies/S-EPMC2596068biostudies-literatureUnknown8(20)The high facioselectivity in the epoxidation of 4-deoxypentenosides (4-DPs) by dimethyldioxirane (DMDO) correlates with a stereoelectronic bias in the 4-DPs' ground-state conformations, as elucidated by polarized-pi frontier molecular orbital (PPFMO) analysis.Organic lettersStereoselective epoxidation of 4-deoxypentenosides: a polarized-pi model.PMC2596068R01 GM069862GM-06982-01R01 GM069862-04Wenthold PGWei AShi QCheng GBoulineau FPLiew STfalseStereoselective epoxidation of 4-deoxypentenosides: a polarized-pi model.The high facioselectivity in the epoxidation of 4-deoxypentenosides (4-DPs) by dimethyldioxirane (DMDO) correlates with a stereoelectronic bias in the 4-DPs' ground-state conformations, as elucidated by polarized-pi frontier molecular orbital (PPFMO) analysis.2006-01-01T00:00:00Z2006 Sep2020-11-01T08:15:40Z2019-03-27T00:19:38ZS-EPMC25960681698694610.1021/ol0617401