{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Rarig RA"],"funding":["NIGMS NIH HHS"],"pagination":["9182-3"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2646882"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["130(29)"],"pubmed_abstract":["Metal-free homoallylic oxygen-directed intramolecular hydroboration is reported. Regioselectivities from 20:1 to 82:1 favoring the 1,3-dioxy-substituted products have been achieved using Me2S.BH3/TfOH followed by standard oxidative workup. Branching at the C5 position improves regioselectivity."],"journal":["Journal of the American Chemical Society"],"pubmed_title":["Oxygen-directed intramolecular hydroboration."],"pmcid":["PMC2646882"],"funding_grant_id":["T32 GM008597","R01 GM067146","GM067146","GM08597"],"pubmed_authors":["Rarig RA","Scheideman M","Vedejs E"],"additional_accession":[]},"is_claimable":false,"name":"Oxygen-directed intramolecular hydroboration.","description":"Metal-free homoallylic oxygen-directed intramolecular hydroboration is reported. Regioselectivities from 20:1 to 82:1 favoring the 1,3-dioxy-substituted products have been achieved using Me2S.BH3/TfOH followed by standard oxidative workup. Branching at the C5 position improves regioselectivity.","dates":{"release":"2008-01-01T00:00:00Z","publication":"2008 Jul","modification":"2025-04-04T07:58:21.803Z","creation":"2019-03-27T00:20:52Z"},"accession":"S-EPMC2646882","cross_references":{"pubmed":["18572941"],"doi":["10.1021/ja800402g"]}}