biostudies-literature00460Tarselli MANIGMS NIH HHS4596-9https://www.ebi.ac.uk/biostudies/studies/S-EPMC2818175biostudies-literatureUnknown11(20)A procedure for the coupling of aliphatic imines with allylic and allenic alkoxides is described. The success of these studies was enabled by a unique reactivity profile of Ti(IV) isopropoxide/n-BuLi compared to well-known Ti(IV) isopropoxide/RMgX systems.Organic lettersAliphatic imines in titanium-mediated reductive cross-coupling: unique reactivity of Ti(O-i-Pr)4/n-BuLi.PMC2818175R01 GM080266-01R01 GM080266R01 GM080266-03R01 GM080266-02R01 GM080266-04R01 GM080266-04S1GM80266Tarselli MAMicalizio GC46falseAliphatic imines in titanium-mediated reductive cross-coupling: unique reactivity of Ti(O-i-Pr)4/n-BuLi.A procedure for the coupling of aliphatic imines with allylic and allenic alkoxides is described. The success of these studies was enabled by a unique reactivity profile of Ti(IV) isopropoxide/n-BuLi compared to well-known Ti(IV) isopropoxide/RMgX systems.2009-01-01T00:00:00Z2009 Oct2024-10-15T21:24:01.843Z2019-03-27T00:28:25ZS-EPMC28181751981076510.1021/ol901870n