biostudies-literature00540UnknownBall NDNIGMS NIH HHSThis article describes the synthesis, characterization, and reactivity of palladium(II) fluoride complexes containing sp(2) and sp(3) nitrogen-containing supporting ligands. Both cis and trans complexes of general structure (N)(N')Pd(II)(R)(F) (R = Ar or CH(3)) as well as cis-(N)(2)Pd(II)(F)(2) are reported. Crystallographic characterization of these molecules has allowed structural comparisons to related phosphine-ligated species. Furthermore, these studies have revealed that nitrogen-donor ligands support some of the longest and the shortest Pd-F bonds reported to date. The thermal decomposition of (N)(N')Pd(II)(R)(F) has also been examined, and no products of C-F bond-forming reductive elimination were obtained in any case.Dalton transactions (Cambridge, England : 2003)632-40https://www.ebi.ac.uk/biostudies/studies/S-EPMC2855696biostudies-literatureSynthesis and reactivity of palladium(II) fluoride complexes containing nitrogen-donor ligands.PMC2855696F31 GM089141R01 GM073836-05R01-GM073836F31-GM089141F31 GM089141-01R01 GM073836Ball NDSanford MSKampf JW54falseSynthesis and reactivity of palladium(II) fluoride complexes containing nitrogen-donor ligands.This article describes the synthesis, characterization, and reactivity of palladium(II) fluoride complexes containing sp(2) and sp(3) nitrogen-containing supporting ligands. Both cis and trans complexes of general structure (N)(N')Pd(II)(R)(F) (R = Ar or CH(3)) as well as cis-(N)(2)Pd(II)(F)(2) are reported. Crystallographic characterization of these molecules has allowed structural comparisons to related phosphine-ligated species. Furthermore, these studies have revealed that nitrogen-donor ligands support some of the longest and the shortest Pd-F bonds reported to date. The thermal decomposition of (N)(N')Pd(II)(R)(F) has also been examined, and no products of C-F bond-forming reductive elimination were obtained in any case.2010-01-01T00:00:00Z2010 Jan2024-11-19T23:47:31.858Z2019-03-26T22:30:12ZS-EPMC28556962002400210.1039/b914426a