{"database":"biostudies-literature","file_versions":[],"scores":{"citationCount":0,"reanalysisCount":0,"viewCount":61,"searchCount":0},"additional":{"submitter":["Herrmann AT"],"funding":["NIGMS NIH HHS"],"pagination":["5962-3"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2861154"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["132(17)"],"pubmed_abstract":["A hydroxyl group-directed, highly regio- and stereoselective transposition of allylic alcohols based on rhenium catalysis has been developed. The method is suitable for a direct isomerization of acetals into the thermodynamically preferred isomer as long as one of the hydroxyl groups is allylic. This method will expand the scope of rhenium-catalyzed alcohol transpositions for complex molecule synthesis."],"journal":["Journal of the American Chemical Society"],"pubmed_title":["Regio- and stereocontrol in rhenium-catalyzed transposition of allylic alcohols."],"pmcid":["PMC2861154"],"funding_grant_id":["R01 GM077379-02","R01 GM077379"],"pubmed_authors":["Saito T","Zakarian A","Herrmann AT","Stivala CE","Tom J"],"view_count":["61"],"additional_accession":[]},"is_claimable":false,"name":"Regio- and stereocontrol in rhenium-catalyzed transposition of allylic alcohols.","description":"A hydroxyl group-directed, highly regio- and stereoselective transposition of allylic alcohols based on rhenium catalysis has been developed. The method is suitable for a direct isomerization of acetals into the thermodynamically preferred isomer as long as one of the hydroxyl groups is allylic. This method will expand the scope of rhenium-catalyzed alcohol transpositions for complex molecule synthesis.","dates":{"release":"2010-01-01T00:00:00Z","publication":"2010 May","modification":"2020-11-01T08:13:43Z","creation":"2019-03-26T23:28:37Z"},"accession":"S-EPMC2861154","cross_references":{"pubmed":["20387811"],"doi":["10.1021/ja101673v"]}}