{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Kong J"],"funding":["NHGRI NIH HHS"],"pagination":["m18"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2914910"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["64(Pt 1)"],"pubmed_abstract":["The title complex, [Ni(2)(C(42)H(46)Cl(2)N(6)O(2))(C(2)H(3)O(2))]ClO(4)·2CH(3)CN, was synthesized by condensation of 2,6-diformyl-4-chloro-phenol with N,N-bis-(amino-prop-yl)benzyl-amine in the presence of Ni(II) ions. The ligand is a 28-membered macrocycle with two identical pendant arms. The coordination geometries of the Ni atoms are both octa-hedral. The two Ni atoms are bridged by two phenolate O atoms of the macrocyclic ligand and one acetate ligand, with an Ni⋯Ni distance of 3.147 (4) Å."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pubmed_title":["μ-Acetato-κO:O'-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa-azatri-cyclo-[27.3.1.1]tetra-triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca-ene-33,34-diolato-κN,N,N,O,O:N,N,N,O,O]dinickel(II) per-chlorate acetonitrile disolvate."],"pmcid":["PMC2914910"],"funding_grant_id":["P50 HG002351"],"pubmed_authors":["Pan ZQ","Kong J","Zhou H"],"additional_accession":[]},"is_claimable":false,"name":"μ-Acetato-κO:O'-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa-azatri-cyclo-[27.3.1.1]tetra-triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca-ene-33,34-diolato-κN,N,N,O,O:N,N,N,O,O]dinickel(II) per-chlorate acetonitrile disolvate.","description":"The title complex, [Ni(2)(C(42)H(46)Cl(2)N(6)O(2))(C(2)H(3)O(2))]ClO(4)·2CH(3)CN, was synthesized by condensation of 2,6-diformyl-4-chloro-phenol with N,N-bis-(amino-prop-yl)benzyl-amine in the presence of Ni(II) ions. The ligand is a 28-membered macrocycle with two identical pendant arms. The coordination geometries of the Ni atoms are both octa-hedral. The two Ni atoms are bridged by two phenolate O atoms of the macrocyclic ligand and one acetate ligand, with an Ni⋯Ni distance of 3.147 (4) Å.","dates":{"release":"2007-01-01T00:00:00Z","publication":"2007 Dec","modification":"2025-04-22T02:47:26.997Z","creation":"2019-03-27T00:32:56Z"},"accession":"S-EPMC2914910","cross_references":{"pubmed":["21200528"],"doi":["10.1107/S1600536807061399"]}}