<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>64(Pt 11)</volume><submitter>Dong WK</submitter><pubmed_abstract>In the title compound, C(21)H(26)N(2)O(4), there is half a mol-ecule in the asymmetric unit with a crystallographic twofold rotation axis passing through the central C atom of the -CH=N-O-(CH(2))(5)-O-N=CH- bridge. The dihedral angle formed by the two benzene rings is 80.85 (2)°. Strong intra-molecular O-H⋯N and C-H⋯O hydrogen bonds help to establish the molecular conformation. There are also weak inter-molecular π-π stacking inter-actions between neighbouring benzene rings [centroid-centroid separation = 3.502 (3) Å].</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o2059</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2959680</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>2,2'-{1,1'-[Pentane-1,5-diyl-bis(oxy-nitrilo)]-diethyl-idyne}diphenol.</pubmed_title><pmcid>PMC2959680</pmcid><pubmed_authors>Lv ZW</pubmed_authors><pubmed_authors>Tong JF</pubmed_authors><pubmed_authors>He XN</pubmed_authors><pubmed_authors>Guan YH</pubmed_authors><pubmed_authors>Dong WK</pubmed_authors></additional><is_claimable>false</is_claimable><name>2,2'-{1,1'-[Pentane-1,5-diyl-bis(oxy-nitrilo)]-diethyl-idyne}diphenol.</name><description>In the title compound, C(21)H(26)N(2)O(4), there is half a mol-ecule in the asymmetric unit with a crystallographic twofold rotation axis passing through the central C atom of the -CH=N-O-(CH(2))(5)-O-N=CH- bridge. The dihedral angle formed by the two benzene rings is 80.85 (2)°. Strong intra-molecular O-H⋯N and C-H⋯O hydrogen bonds help to establish the molecular conformation. There are also weak inter-molecular π-π stacking inter-actions between neighbouring benzene rings [centroid-centroid separation = 3.502 (3) Å].</description><dates><release>2008-01-01T00:00:00Z</release><publication>2008 Oct</publication><modification>2025-06-01T01:13:20.361Z</modification><creation>2025-06-01T01:13:20.361Z</creation></dates><accession>S-EPMC2959680</accession><cross_references><pubmed>21580925</pubmed><doi>10.1107/S160053680803136X</doi></cross_references></HashMap>