<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>64(Pt 11)</volume><submitter>Lin CS</submitter><pubmed_abstract>The Cu(II) atom in the title complex, [Cu(C(18)H(21)N(2)O(2))(C(2)H(3)O(2))], is tetra-coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra-molecular inter-action toward the Cu atom, the Cu-O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak inter-molecular inter-actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu-O distance in other crystal structures.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m1434</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2959767</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>(Acetato-κO)(2-{[2-(dimethyl-amino)-ethyl-imino](phen-yl)meth-yl}-5-methoxy-phenolato-κN,N',O)copper(II).</pubmed_title><pmcid>PMC2959767</pmcid><pubmed_authors>Huang JH</pubmed_authors><pubmed_authors>Lin CS</pubmed_authors><pubmed_authors>Ko BT</pubmed_authors><pubmed_authors>Lin CH</pubmed_authors></additional><is_claimable>false</is_claimable><name>(Acetato-κO)(2-{[2-(dimethyl-amino)-ethyl-imino](phen-yl)meth-yl}-5-methoxy-phenolato-κN,N',O)copper(II).</name><description>The Cu(II) atom in the title complex, [Cu(C(18)H(21)N(2)O(2))(C(2)H(3)O(2))], is tetra-coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra-molecular inter-action toward the Cu atom, the Cu-O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak inter-molecular inter-actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu-O distance in other crystal structures.</description><dates><release>2008-01-01T00:00:00Z</release><publication>2008 Oct</publication><modification>2024-11-13T17:34:55.867Z</modification><creation>2019-03-26T23:59:48Z</creation></dates><accession>S-EPMC2959767</accession><cross_references><pubmed>21580877</pubmed><doi>10.1107/S1600536808033114</doi></cross_references></HashMap>