{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["64(Pt 12)"],"submitter":["Wang LG"],"pubmed_abstract":["The Co(II) ion in the title complex, [Co(2)(C(4)H(5)O(2))(4)(C(15)H(13)N(5))(2)]·2H(2)O, has a distorted square-planar coordination formed by the bridging bidentate N,N'-di-4-pyridylpyrid-ine-2,6-diamine (dapmp) ligands and two monodentate carboxyl-ate groups from methacrylates. Two dapmp ligands bridge two Co atoms, forming a dinuclear complex arranged around an inversion centre. N-H⋯O and O-H⋯O hydrogen bonds involving the solvent water mol-ecule result in the formation of a three-dimensional network. The aliphatic moiety of one of the methacrylate groups is disordered over two positions with fixed occupancies of 0.67 and 0.33."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1579"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2959996"],"repository":["biostudies-literature"],"pubmed_title":["Bis(μ-N,N'-di-4-pyridylpyridine-2,6-diamine)bis[dimethacrylatocobalt(II)] dihydrate."],"pmcid":["PMC2959996"],"pubmed_authors":["Peng AH","Wang LG"],"additional_accession":[]},"is_claimable":false,"name":"Bis(μ-N,N'-di-4-pyridylpyridine-2,6-diamine)bis[dimethacrylatocobalt(II)] dihydrate.","description":"The Co(II) ion in the title complex, [Co(2)(C(4)H(5)O(2))(4)(C(15)H(13)N(5))(2)]·2H(2)O, has a distorted square-planar coordination formed by the bridging bidentate N,N'-di-4-pyridylpyrid-ine-2,6-diamine (dapmp) ligands and two monodentate carboxyl-ate groups from methacrylates. Two dapmp ligands bridge two Co atoms, forming a dinuclear complex arranged around an inversion centre. N-H⋯O and O-H⋯O hydrogen bonds involving the solvent water mol-ecule result in the formation of a three-dimensional network. The aliphatic moiety of one of the methacrylate groups is disordered over two positions with fixed occupancies of 0.67 and 0.33.","dates":{"release":"2008-01-01T00:00:00Z","publication":"2008 Nov","modification":"2025-04-18T12:28:05.793Z","creation":"2019-03-26T23:59:50Z"},"accession":"S-EPMC2959996","cross_references":{"pubmed":["21581181"],"doi":["10.1107/S1600536808037847"]}}