{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["64(Pt 2)"],"submitter":["Han JH"],"pubmed_abstract":["In the centrosymmetric title compound, [Ni(C(6)H(4)NO(2))(2)(C(22)H(34)N(6))], the Ni(II) ion is bonded to the four secondary N atoms of the macrocyclic ligand in a square-planar fashion and two carboxyl-ate O atoms of the isonicotinate ions in axial positions, resulting in a tetra-gonally distorted octa-hedron. An offset face-to-face π-π stacking inter-action [centroid-centroid distance = 3.674(4) Å] and N-H⋯N and N-H⋯O hydrogen-bonding inter-actions give rise to a one-dimensional supra-molecular structure in the solid state."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m366"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2960468"],"repository":["biostudies-literature"],"pubmed_title":["trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexa-azacyclo-tetra-deca-ne)diisonicotinatonickel(II)."],"pmcid":["PMC2960468"],"pubmed_authors":["Kim BG","Min KS","Han JH"],"additional_accession":[]},"is_claimable":false,"name":"trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexa-azacyclo-tetra-deca-ne)diisonicotinatonickel(II).","description":"In the centrosymmetric title compound, [Ni(C(6)H(4)NO(2))(2)(C(22)H(34)N(6))], the Ni(II) ion is bonded to the four secondary N atoms of the macrocyclic ligand in a square-planar fashion and two carboxyl-ate O atoms of the isonicotinate ions in axial positions, resulting in a tetra-gonally distorted octa-hedron. An offset face-to-face π-π stacking inter-action [centroid-centroid distance = 3.674(4) Å] and N-H⋯N and N-H⋯O hydrogen-bonding inter-actions give rise to a one-dimensional supra-molecular structure in the solid state.","dates":{"release":"2008-01-01T00:00:00Z","publication":"2008 Jan","modification":"2024-10-16T02:10:44.676Z","creation":"2019-03-26T23:59:52Z"},"accession":"S-EPMC2960468","cross_references":{"pubmed":["21201324"],"doi":["10.1107/S1600536808001116"]}}