<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>64(Pt 9)</volume><submitter>Zhang SG</submitter><pubmed_abstract>In the title complex, [Zn(C(10)H(7)N(2)O(2))(2)(H(2)O)], the Zn(II) ion and water O atom are located on a crystallographic twofold rotation axis and the metal atom assumes a distorted trigonal-bipyramidal ZnN(4)O coordination geometry. An intra-molecular O-H?O hydrogen bond occurs within the ligand and inter-molecular O-H?O hydrogen bonds involving the water mol-ecule result in a sheet structure in the crystal structure. In addition, a short C-O?? contact between the O atom of the deprotonated hydroxyl group and a nearby pyridine ring [O?Cg = 3.977?(2)?Å, where Cg is the centroid of the pyridine ring] is observed.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m1131</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2960646</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Aqua-bis(3'-hydr-oxy-2,2'-bipyridine-3-olato-?N,N')zinc(II).</pubmed_title><pmcid>PMC2960646</pmcid><pubmed_authors>Hou C</pubmed_authors><pubmed_authors>Zhang SG</pubmed_authors></additional><is_claimable>false</is_claimable><name>Aqua-bis(3'-hydr-oxy-2,2'-bipyridine-3-olato-?N,N')zinc(II).</name><description>In the title complex, [Zn(C(10)H(7)N(2)O(2))(2)(H(2)O)], the Zn(II) ion and water O atom are located on a crystallographic twofold rotation axis and the metal atom assumes a distorted trigonal-bipyramidal ZnN(4)O coordination geometry. An intra-molecular O-H?O hydrogen bond occurs within the ligand and inter-molecular O-H?O hydrogen bonds involving the water mol-ecule result in a sheet structure in the crystal structure. In addition, a short C-O?? contact between the O atom of the deprotonated hydroxyl group and a nearby pyridine ring [O?Cg = 3.977?(2)?Å, where Cg is the centroid of the pyridine ring] is observed.</description><dates><release>2008-01-01T00:00:00Z</release><publication>2008 Aug</publication><modification>2021-03-03T08:36:56Z</modification><creation>2019-03-26T23:59:53Z</creation></dates><accession>S-EPMC2960646</accession><cross_references><pubmed>21201589</pubmed><doi>10.1107/S1600536808024495</doi></cross_references></HashMap>