{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Ali BF"],"funding":["NCCIH NIH HHS"],"pagination":["m485-6"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2960811"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["64(Pt 3)"],"pubmed_abstract":["In the crystal structure of the title compound, (C(7)H(10)N)(2)[CoBr(4)], the [CoBr(4)](2-) anion is connected to two cations through N-H⋯Br and H(2)C-H⋯Br hydrogen bonds to form two-dimensional cation-anion-cation layers normal to the crystallographic b axis. Inter-actions of the π-π type are absent between cations in the stacks [centroid-centroid separation = 5.01 (5) Å]. Significant inter-molecular Br-aryl inter-actions are present in the structure, especially an unusually short Br-ring centroid inter-action of 3.78 (1) Å. The coordination geometry of the anion is approximately tetrahedral and a twofold rotation axis passes through the Co atom."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pubmed_title":["Bis(2,6-dimethyl-pyridinium) tetra-bromido-cobaltate(II)."],"pmcid":["PMC2960811"],"funding_grant_id":["R01 AT002543"],"pubmed_authors":["Al-Far RH","Ali BF","Haddad SF"],"additional_accession":[]},"is_claimable":false,"name":"Bis(2,6-dimethyl-pyridinium) tetra-bromido-cobaltate(II).","description":"In the crystal structure of the title compound, (C(7)H(10)N)(2)[CoBr(4)], the [CoBr(4)](2-) anion is connected to two cations through N-H⋯Br and H(2)C-H⋯Br hydrogen bonds to form two-dimensional cation-anion-cation layers normal to the crystallographic b axis. Inter-actions of the π-π type are absent between cations in the stacks [centroid-centroid separation = 5.01 (5) Å]. Significant inter-molecular Br-aryl inter-actions are present in the structure, especially an unusually short Br-ring centroid inter-action of 3.78 (1) Å. The coordination geometry of the anion is approximately tetrahedral and a twofold rotation axis passes through the Co atom.","dates":{"release":"2008-01-01T00:00:00Z","publication":"2008 Feb","modification":"2025-05-18T12:55:12.388Z","creation":"2025-05-18T12:55:12.388Z"},"accession":"S-EPMC2960811","cross_references":{"pubmed":["21201870"],"doi":["10.1107/S160053680800439X"]}}