biostudies-literatureUnknown64(Pt 4)Navarro MIn the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetra-hedrally coordinated by a bidentate 2,2'-bipyridine ligand and two PPh(3) ligands. The Cu-N and Cu-P distances are similar to those observed in similar compounds. The range of coordination angles shows a moderate distortion from ideal tetra-hedral geometry. The bipyridine ligand is twisted [14.2 (4)°] about the ring-ring C-C bond. The nitrate anion and the water and chloro-form mol-ecules of solvation are disordered. In the crystal structure, there are O(water)-H⋯O(nitrate), C-H⋯O(water) and C-H⋯O(nitrate) hydrogen bonds.Acta crystallographica. Section E, Structure reports onlinem533-4https://www.ebi.ac.uk/biostudies/studies/S-EPMC2960891biostudies-literature(2,2'-Bipyridine)bis-(triphenyl-phosphine)copper(I) nitrate chloro-form solvate hemihydrate.PMC2960891Corona OANavarro MGonzalez TCapparelli MVfalse(2,2'-Bipyridine)bis-(triphenyl-phosphine)copper(I) nitrate chloro-form solvate hemihydrate.In the title compound, [Cu(C(10)H(8)N(2))(C(18)H(15)P)(2)]NO(2)·CHCl(3)·0.5H(2)O, the Cu atom is tetra-hedrally coordinated by a bidentate 2,2'-bipyridine ligand and two PPh(3) ligands. The Cu-N and Cu-P distances are similar to those observed in similar compounds. The range of coordination angles shows a moderate distortion from ideal tetra-hedral geometry. The bipyridine ligand is twisted [14.2 (4)°] about the ring-ring C-C bond. The nitrate anion and the water and chloro-form mol-ecules of solvation are disordered. In the crystal structure, there are O(water)-H⋯O(nitrate), C-H⋯O(water) and C-H⋯O(nitrate) hydrogen bonds.2008-01-01T00:00:00Z2008 Mar2025-05-18T12:55:43.86Z2025-05-18T12:55:43.86ZS-EPMC29608912120199510.1107/S1600536808006260