{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["64(Pt 6)"],"submitter":["Jia L"],"pubmed_abstract":["The title compound, [Cu(2){SC(NH(2))NHNH(2)}(6)]I(2), was obtained by the reaction of CuI and thio-semicarbazide (TSCZ) in acetonitrile. Each Cu(I) ion is coordinated by four S atoms of the TSCZ ligands, forming a tetra-hedral geometry. Centrosymmetric dimers are formed by two coordination tetra-hedra sharing a common edge, with a Cu⋯Cu distance of 2.8236 (14) Å. The I(-) ion does not have any direct inter-action with the metal. The crystal structure is stabilized by weak N-H⋯N, N-H⋯S and N-H⋯I hydrogen bonds, forming a three-dimensional network structure."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m820"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2961471"],"repository":["biostudies-literature"],"pubmed_title":["Di-μ-thio-semicarbazide-κS:S-bis-[bis-(thio-semicarbazide-κS)copper(I)] diiodide."],"pmcid":["PMC2961471"],"pubmed_authors":["Ma SX","Jia L","Li DC"],"additional_accession":[]},"is_claimable":false,"name":"Di-μ-thio-semicarbazide-κS:S-bis-[bis-(thio-semicarbazide-κS)copper(I)] diiodide.","description":"The title compound, [Cu(2){SC(NH(2))NHNH(2)}(6)]I(2), was obtained by the reaction of CuI and thio-semicarbazide (TSCZ) in acetonitrile. Each Cu(I) ion is coordinated by four S atoms of the TSCZ ligands, forming a tetra-hedral geometry. Centrosymmetric dimers are formed by two coordination tetra-hedra sharing a common edge, with a Cu⋯Cu distance of 2.8236 (14) Å. The I(-) ion does not have any direct inter-action with the metal. The crystal structure is stabilized by weak N-H⋯N, N-H⋯S and N-H⋯I hydrogen bonds, forming a three-dimensional network structure.","dates":{"release":"2008-01-01T00:00:00Z","publication":"2008 May","modification":"2025-04-26T18:59:51.952Z","creation":"2019-03-27T00:00:00Z"},"accession":"S-EPMC2961471","cross_references":{"pubmed":["21202503"],"doi":["10.1107/S1600536808014001"]}}