biostudies-literatureUnknown64(Pt 6)Jia LThe title compound, [Cu(2){SC(NH(2))NHNH(2)}(6)]I(2), was obtained by the reaction of CuI and thio-semicarbazide (TSCZ) in acetonitrile. Each Cu(I) ion is coordinated by four S atoms of the TSCZ ligands, forming a tetra-hedral geometry. Centrosymmetric dimers are formed by two coordination tetra-hedra sharing a common edge, with a Cu⋯Cu distance of 2.8236 (14) Å. The I(-) ion does not have any direct inter-action with the metal. The crystal structure is stabilized by weak N-H⋯N, N-H⋯S and N-H⋯I hydrogen bonds, forming a three-dimensional network structure.Acta crystallographica. Section E, Structure reports onlinem820https://www.ebi.ac.uk/biostudies/studies/S-EPMC2961471biostudies-literatureDi-μ-thio-semicarbazide-κS:S-bis-[bis-(thio-semicarbazide-κS)copper(I)] diiodide.PMC2961471Ma SXJia LLi DCfalseDi-μ-thio-semicarbazide-κS:S-bis-[bis-(thio-semicarbazide-κS)copper(I)] diiodide.The title compound, [Cu(2){SC(NH(2))NHNH(2)}(6)]I(2), was obtained by the reaction of CuI and thio-semicarbazide (TSCZ) in acetonitrile. Each Cu(I) ion is coordinated by four S atoms of the TSCZ ligands, forming a tetra-hedral geometry. Centrosymmetric dimers are formed by two coordination tetra-hedra sharing a common edge, with a Cu⋯Cu distance of 2.8236 (14) Å. The I(-) ion does not have any direct inter-action with the metal. The crystal structure is stabilized by weak N-H⋯N, N-H⋯S and N-H⋯I hydrogen bonds, forming a three-dimensional network structure.2008-01-01T00:00:00Z2008 May2025-04-26T18:59:51.952Z2019-03-27T00:00:00ZS-EPMC29614712120250310.1107/S1600536808014001