{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["65(Pt 1)"],"submitter":["Wang CJ"],"pubmed_abstract":["In the title compound, [Ni(C(8)H(7)O(3))(C(10)H(8)N(2))]ClO(4), the Ni(II) atom is in a slightly distorted square-planar coordination by two N atoms from the 2,2'-bipyridine (bipy) ligand and two O atoms from the deprotonated 2-formyl-6-methoxy-phenolate (mbd) ligand. The bipy ligand is nearly coplanar with the Ni(II) square plane, the Ni atom being only 0.042 (2) Å from the mean plane, whereas the benzaldehyde plane is folded with respect to the square plane, making a dihedral angle of 19.17 (8)°. One of the O atoms of the perchlorate anion is involved in a weak inter-action with the Ni atom, with an Ni-O distance of 2.5732 (18) Å. The packing is stabilized by weak C-H⋯O inter-actions."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m11"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2967862"],"repository":["biostudies-literature"],"pubmed_title":["(2,2'-Bipyridine)(2-formyl-6-methoxy-phenolato)nickel(II) perchlorate."],"pmcid":["PMC2967862"],"pubmed_authors":["Wu WP","Wang CJ","Ren PD","Zhang ZB"],"additional_accession":[]},"is_claimable":false,"name":"(2,2'-Bipyridine)(2-formyl-6-methoxy-phenolato)nickel(II) perchlorate.","description":"In the title compound, [Ni(C(8)H(7)O(3))(C(10)H(8)N(2))]ClO(4), the Ni(II) atom is in a slightly distorted square-planar coordination by two N atoms from the 2,2'-bipyridine (bipy) ligand and two O atoms from the deprotonated 2-formyl-6-methoxy-phenolate (mbd) ligand. The bipy ligand is nearly coplanar with the Ni(II) square plane, the Ni atom being only 0.042 (2) Å from the mean plane, whereas the benzaldehyde plane is folded with respect to the square plane, making a dihedral angle of 19.17 (8)°. One of the O atoms of the perchlorate anion is involved in a weak inter-action with the Ni atom, with an Ni-O distance of 2.5732 (18) Å. The packing is stabilized by weak C-H⋯O inter-actions.","dates":{"release":"2008-01-01T00:00:00Z","publication":"2008 Dec","modification":"2025-04-05T00:26:51.053Z","creation":"2019-03-27T00:00:03Z"},"accession":"S-EPMC2967862","cross_references":{"pubmed":["21581476"],"doi":["10.1107/S1600536808040385"]}}