{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["65(Pt 1)"],"submitter":["Zeng W"],"pubmed_abstract":["In the title compound, [Ni(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the complete dimeric complex is generated by an inversion center. The Ni(II) atoms are octa-hedrally coordinated by two N atoms from one 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand and two O atoms from two adjacent sulfate ions forming the equatorial plane, with two coordinated water mol-ecules in the axial sites. Both of the sulfate ions act as bidentate-bridging ligands connecting the two Ni(II) ions, thus generating a binuclear complex. In the crystal structure, O-H⋯O and O-H⋯N hydrogen bonds involving the coordinated and uncoordinated water mol-ecules and N-H⋯O links lead to the formation of a two-dimensional sheet structure developing parallel to (010). Weak π-π stacking inter-actions [centroid-centroid"],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m42-3"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2967888"],"repository":["biostudies-literature"],"pubmed_title":["Di-μ-sulfato-bis-[diaqua-(1H-imidazo[4,5-f][1,10]phenanthroline)nickel(II)] dihydrate."],"pmcid":["PMC2967888"],"pubmed_authors":["Fang Y","She JH","Wang CJ","Zeng W"],"additional_accession":[]},"is_claimable":false,"name":"Di-μ-sulfato-bis-[diaqua-(1H-imidazo[4,5-f][1,10]phenanthroline)nickel(II)] dihydrate.","description":"In the title compound, [Ni(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the complete dimeric complex is generated by an inversion center. The Ni(II) atoms are octa-hedrally coordinated by two N atoms from one 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand and two O atoms from two adjacent sulfate ions forming the equatorial plane, with two coordinated water mol-ecules in the axial sites. Both of the sulfate ions act as bidentate-bridging ligands connecting the two Ni(II) ions, thus generating a binuclear complex. In the crystal structure, O-H⋯O and O-H⋯N hydrogen bonds involving the coordinated and uncoordinated water mol-ecules and N-H⋯O links lead to the formation of a two-dimensional sheet structure developing parallel to (010). Weak π-π stacking inter-actions [centroid-centroid","dates":{"release":"2008-01-01T00:00:00Z","publication":"2008 Dec","modification":"2025-04-05T00:26:26.488Z","creation":"2019-03-27T00:00:51Z"},"accession":"S-EPMC2967888","cross_references":{"pubmed":["21581515"],"doi":["10.1107/S1600536808040634"]}}